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Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling

This thesis aims to discuss the potential of using piezoelectric and triboelectric nanogenerators (PTENGs) for energy harvesting, particularly in the sportswear industry. PTENG's main advantage is that it offers good flexibility making it suitable for high-strain applications. The piezoelectric effe...

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Main Author: El Toukhy, Khaled
Format: Thesis
Published: AUC Knowledge Fountain 2023
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access_status_str Open Access
author El Toukhy, Khaled
author_browse El Toukhy, Khaled
author_facet El Toukhy, Khaled
author_sort El Toukhy, Khaled
collection Thesis
description This thesis aims to discuss the potential of using piezoelectric and triboelectric nanogenerators (PTENGs) for energy harvesting, particularly in the sportswear industry. PTENG's main advantage is that it offers good flexibility making it suitable for high-strain applications. The piezoelectric effect is induced by embedding piezoelectric nanofillers into one of the two triboelectric layers. PTENGs can generate both piezoelectric and triboelectric signals when strained resulting in an enhanced output compared to regular piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs). TPU was adopted as the matrix for PTENGs advantageous due to their flexibility, low electrical resistivity, and compatibility with additive manufacturing techniques. In this study, a nanocomposite of TPU/ZnO of two different weight percentages (20% ZnO and 15% ZnO) was fabricated using a solution mixing method and subsequently turned into a filament for 3D printing. When applying 5 N, the PENG generated peak potential differences ranging from 3.455 mV to 2630 mV, depending on the weight percentage of ZnO used. Additionally, a cyclic loading test, simulating average walking speed and running, using a layer of 15wt% ZnO/TPU and Ecoflex was done. The surface area of the PTENG and the thickness of the Ecoflex layer varied to test its effect on the performance of the PTENG. The best-performing PTENG under the running cyclic loading resulted in a peak potential difference of 40 V for the piezoelectric response and 67.2 V for the triboelectric response. For the walking test, the best performance was recorded to have a peak potential difference of 22 V and 23.6 V. However, the 20wt% ZnO/TPU layer was not used in the fabrication of the PTENG due to its brittleness causing filament failure or nozzle clogging making it unreliable for long printing hours. These findings highlight the potential of PTENGs in energy harvesting applications, particularly in the sportswear industry, where customized dimensions and enhanced energy harvesting capabilities can be achieved especially in show sole manufacturing which already uses TPU as their go-to material.
format Thesis
id oai:fount.aucegypt.edu:etds-3236
institution American University in Cairo (Egypt)
last_indexed 2026-06-10T12:35:54.296Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from AUC Knowledge Fountain — bepress
publishDate 2023
publishDateRange 2023
publishDateSort 2023
publisher AUC Knowledge Fountain
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source_str AUC Knowledge Fountain — bepress
spelling oai:fount.aucegypt.edu:etds-3236 Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling El Toukhy, Khaled This thesis aims to discuss the potential of using piezoelectric and triboelectric nanogenerators (PTENGs) for energy harvesting, particularly in the sportswear industry. PTENG's main advantage is that it offers good flexibility making it suitable for high-strain applications. The piezoelectric effect is induced by embedding piezoelectric nanofillers into one of the two triboelectric layers. PTENGs can generate both piezoelectric and triboelectric signals when strained resulting in an enhanced output compared to regular piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs). TPU was adopted as the matrix for PTENGs advantageous due to their flexibility, low electrical resistivity, and compatibility with additive manufacturing techniques. In this study, a nanocomposite of TPU/ZnO of two different weight percentages (20% ZnO and 15% ZnO) was fabricated using a solution mixing method and subsequently turned into a filament for 3D printing. When applying 5 N, the PENG generated peak potential differences ranging from 3.455 mV to 2630 mV, depending on the weight percentage of ZnO used. Additionally, a cyclic loading test, simulating average walking speed and running, using a layer of 15wt% ZnO/TPU and Ecoflex was done. The surface area of the PTENG and the thickness of the Ecoflex layer varied to test its effect on the performance of the PTENG. The best-performing PTENG under the running cyclic loading resulted in a peak potential difference of 40 V for the piezoelectric response and 67.2 V for the triboelectric response. For the walking test, the best performance was recorded to have a peak potential difference of 22 V and 23.6 V. However, the 20wt% ZnO/TPU layer was not used in the fabrication of the PTENG due to its brittleness causing filament failure or nozzle clogging making it unreliable for long printing hours. These findings highlight the potential of PTENGs in energy harvesting applications, particularly in the sportswear industry, where customized dimensions and enhanced energy harvesting capabilities can be achieved especially in show sole manufacturing which already uses TPU as their go-to material. 2023-12-30T08:00:00Z thesis application/pdf https://fount.aucegypt.edu/etds/2197 https://fount.aucegypt.edu/context/etds/article/3236/viewcontent/Final_Thesis_Report.pdf Theses and Dissertations AUC Knowledge Fountain Energy Harvesting; Nanocomposite; 3D Printing; Hybrid Nanogenerators; Piezoelectricity; Triboelectricity; Ceramic Filler Ceramic Materials Manufacturing Other Materials Science and Engineering Polymer and Organic Materials
spellingShingle Energy Harvesting; Nanocomposite; 3D Printing; Hybrid Nanogenerators; Piezoelectricity; Triboelectricity; Ceramic Filler
Ceramic Materials
Manufacturing
Other Materials Science and Engineering
Polymer and Organic Materials
El Toukhy, Khaled
Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title_full Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title_fullStr Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title_full_unstemmed Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title_short Fabrication & Characterization of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators via Fusion Deposition Modeling
title_sort fabrication characterization of hybrid piezoelectric triboelectric nanocomposite nanogenerators via fusion deposition modeling
topic Energy Harvesting; Nanocomposite; 3D Printing; Hybrid Nanogenerators; Piezoelectricity; Triboelectricity; Ceramic Filler
Ceramic Materials
Manufacturing
Other Materials Science and Engineering
Polymer and Organic Materials
url https://fount.aucegypt.edu/etds/2197
https://fount.aucegypt.edu/context/etds/article/3236/viewcontent/Final_Thesis_Report.pdf
work_keys_str_mv AT eltoukhykhaled fabricationcharacterizationofhybridpiezoelectrictriboelectricnanocompositenanogeneratorsviafusiondepositionmodeling