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Ammonium hexachlororuthenate precipitation

Ammonium hexachlororuthenate (ACR) is a salt precipitated during a substitution reaction between ammonium and ruthenate dissolved in a strong hydrochloric acid medium. This precipitation reaction is used within the platinum industry as a means of recovering and purifying ruthenium. Application of th...

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Main Author: De Klerk, Frederick Jacobus
Other Authors: Westra, Arjan
Format: Thesis
Language:English
Published: Centre for Bioprocess Engineering Research 2014
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access_status_str Open Access
author De Klerk, Frederick Jacobus
author2 Westra, Arjan
author_browse De Klerk, Frederick Jacobus
Westra, Arjan
author_facet Westra, Arjan
De Klerk, Frederick Jacobus
author_sort De Klerk, Frederick Jacobus
collection Thesis
description Ammonium hexachlororuthenate (ACR) is a salt precipitated during a substitution reaction between ammonium and ruthenate dissolved in a strong hydrochloric acid medium. This precipitation reaction is used within the platinum industry as a means of recovering and purifying ruthenium. Application of this process at the Precious Metals Refinery of Anglo Platinum has brought to light certain inefficiencies. In recent years, volatility in the Ru market price occurred, indicating a potential to benefit financially from an improved Ru recovery. Consequently, this study was conducted to understand the effect of certain parameters on the process of precipitating ammonium hexachlororuthenate.
format Thesis
id oai:open.uct.ac.za:11427/10430
institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:32:45.765Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2014
publishDateRange 2014
publishDateSort 2014
publisher Centre for Bioprocess Engineering Research
publisherStr Centre for Bioprocess Engineering Research
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/10430 Ammonium hexachlororuthenate precipitation De Klerk, Frederick Jacobus Westra, Arjan Hagemann, Justin Petersen, Jochen Bioprocess Engineering Ammonium hexachlororuthenate (ACR) is a salt precipitated during a substitution reaction between ammonium and ruthenate dissolved in a strong hydrochloric acid medium. This precipitation reaction is used within the platinum industry as a means of recovering and purifying ruthenium. Application of this process at the Precious Metals Refinery of Anglo Platinum has brought to light certain inefficiencies. In recent years, volatility in the Ru market price occurred, indicating a potential to benefit financially from an improved Ru recovery. Consequently, this study was conducted to understand the effect of certain parameters on the process of precipitating ammonium hexachlororuthenate. 2014-12-28T15:04:44Z 2014-12-28T15:04:44Z 2011 Master Thesis Masters MSc http://hdl.handle.net/11427/10430 eng application/pdf Centre for Bioprocess Engineering Research Faculty of Engineering and the Built Environment University of Cape Town
spellingShingle Bioprocess Engineering
De Klerk, Frederick Jacobus
Ammonium hexachlororuthenate precipitation
thesis_degree_str Master's
title Ammonium hexachlororuthenate precipitation
title_full Ammonium hexachlororuthenate precipitation
title_fullStr Ammonium hexachlororuthenate precipitation
title_full_unstemmed Ammonium hexachlororuthenate precipitation
title_short Ammonium hexachlororuthenate precipitation
title_sort ammonium hexachlororuthenate precipitation
topic Bioprocess Engineering
url http://hdl.handle.net/11427/10430
work_keys_str_mv AT deklerkfrederickjacobus ammoniumhexachlororuthenateprecipitation