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Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules
Includes bibliographical references.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
Department of Chemistry
2015
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| _version_ | 1867613312424869888 |
|---|---|
| access_status_str | Open Access |
| author | Mehlana, Gift |
| author2 | Bourne, Susan A |
| author_browse | Bourne, Susan A Mehlana, Gift |
| author_facet | Bourne, Susan A Mehlana, Gift |
| author_sort | Mehlana, Gift |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/13360 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:34:08.683Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2015 |
| publishDateRange | 2015 |
| publishDateSort | 2015 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/13360 Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules Mehlana, Gift Bourne, Susan A Ramon, Gaëlle Chemistry Includes bibliographical references. Crystal engineering of metal organic frameworks (MOFs) has developed rapidly over the years. This has been fuelled by useful properties endowed by these materials. MOFs present a unique platform to control chemical and physical properties through manipulation of the components that construct these materials. In this thesis a series of MOFs prepared from 3-(4-pyridyl)benzoate or 4-(4-pyridyl)benzoate with Co(ll), Zn(ll) and Ni(ll) are presented. Most materials were synthesised under solvothermal conditions. The link between the phenyl and pyridyl ring in the ligand allows for conformational change through varying the dihedral angles between these two parts. The carboxylate moiety can also rotate relative to the phenyl ring and its ability to assume different coordination modes under different environments is of utmost importance in achieving flexibility for the design. Structural elucidation of compounds was performed by single crystal X-ray diffraction. Topological analysis was performed on the networks formed by the compounds to have a better understanding of the network connectivity. Bulk material was characterised by thermal methods such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), variable temperature powder X-ray diffraction (PXRD) studies and by hot stage microscopy (HSM). Thermochromic and solvatochromic properties of the activated phases were investigated by spectroscopic techniques. Dynamic motion of the networks upon guest loss and absorption by activated phases were evaluated by single crystal X-ray diffraction studies using Pawley fitting methods. Standard kinetic models were used to analyse the kinetics of guest uptake from isothermal experiments. Non-isothermal experiments were conducted using the TGA and the activation energies were determined for guest desolvation using the Ozawa and Flynn method. 2015-07-03T08:35:27Z 2015-07-03T08:35:27Z 2014 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/13360 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Mehlana, Gift Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| thesis_degree_str | Doctoral |
| title | Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| title_full | Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| title_fullStr | Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| title_full_unstemmed | Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| title_short | Crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| title_sort | crystal engineering of dynamic metal organic frameworks for applications in chromic sensing and capturing of small molecules |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/13360 |
| work_keys_str_mv | AT mehlanagift crystalengineeringofdynamicmetalorganicframeworksforapplicationsinchromicsensingandcapturingofsmallmolecules |