Full Text Available

Note: Clicking the button above will open the full text document at the original institutional repository in a new window.

Flows and fates of nickel-cadmium batteries in the City of Cape Town

Includes bibliographical references .

Saved in:
Bibliographic Details
Main Author: Mason-Jones, Kyle
Other Authors: Von Blottnitz, Harro
Format: Thesis
Language:English
Published: Department of Chemical Engineering 2015
Subjects:
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1867613328697720832
access_status_str Open Access
author Mason-Jones, Kyle
author2 Von Blottnitz, Harro
author_browse Mason-Jones, Kyle
Von Blottnitz, Harro
author_facet Von Blottnitz, Harro
Mason-Jones, Kyle
author_sort Mason-Jones, Kyle
collection Thesis
description Includes bibliographical references .
format Thesis
id oai:open.uct.ac.za:11427/14810
institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:34:23.309Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2015
publishDateRange 2015
publishDateSort 2015
publisher Department of Chemical Engineering
publisherStr Department of Chemical Engineering
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/14810 Flows and fates of nickel-cadmium batteries in the City of Cape Town Mason-Jones, Kyle Von Blottnitz, Harro Chemical Engineering Includes bibliographical references . Current patterns of economic activity entail high rates of material extraction from the natural environment and the generation of large amounts of waste. Alternative strategies must be found if we are to avoid the exhaustion of resources and the environment's capacity to safely absorb our wastes. Examining current resource use is an important step towards achieving a more sustainable society, and the toxic substances widely applied in our technologies form a crucial part of this examination. The heavy metal cadmium is one such substance. The use and disposal of nickel-cadmium secondary cells (the basic components of NiCd batteries) in Cape Town, South Africa, has been investigated with the objective of quantifying the associated flows of cadmium. This was achieved by applying substance flow analysis methodology to the year 2005 with a steady-state approach to quantify the disposal commitment arising from inflows in that year. Uncertainty in the calculated results was quantified by means of Monte Carlo simulation. Small sealed cells were found to make the dominant contribution to overall cadmium flows, with cordless power tools and separately imported cells accounting for most of these. Essentially all of these cells either have or will enter the municipal solid waste streams of the city. Large industrial cells made a smaller but significant contribution to overall inflows (3.4-14%), but none were known to have entered municipal waste. These went primarily to hazardous waste disposal outside the city or recycling abroad, with some going into storage. In order to assess the environmental significance of the cadmium sent to landfill, hypothetical "best worst-case" scenarios were developed which involved the worst case of total cadmium release from landfill, and best-case calculations of the potential contamination of agricultural land that could result from such release. A total release to agriculture was found to contaminate the city's croplands in under twenty years. Although these scenarios considered contamination potential but not the likelihood of contamination, and hence were not predictive, it could nevertheless be concluded that the amounts of cadmium destined for landfill disposal justified concern and caution. The disposal of environmentally significant amounts of cadmium in Cape Town and the very limited understanding of landfill behaviour necessitate the elimination ofNiCd batteries from municipal solid waste streams. Some approaches are briefly discussed by which this might be achieved, with regard to both environmental protection and resource conservation in general and the changing landscape of waste management in South Africa. Significant challenges were encountered from limited data availability during the application of substance flow analysis within a developing-world urban setting. This necessitated primary data collection and adaptation of data from other geographical and temporal scales. Adjusting national data to the city scale required the development of scaling factors which were more plausible than the use of population share or regional GDP Some similarities were noted between the cadmium metabolism of Cape Town and that of previously studied regions in the developed world. This supported the suggestion that some insights from substance flow analysis studies can be transferred to other regions when resources are not available for thorough local study. Important differences were also present, however, and further research is required to develop this possibility. 2015-11-10T14:18:22Z 2015-11-10T14:18:22Z 2009 Master Thesis Masters MSc http://hdl.handle.net/11427/14810 eng application/pdf Department of Chemical Engineering Faculty of Engineering and the Built Environment University of Cape Town
spellingShingle Chemical Engineering
Mason-Jones, Kyle
Flows and fates of nickel-cadmium batteries in the City of Cape Town
thesis_degree_str Master's
title Flows and fates of nickel-cadmium batteries in the City of Cape Town
title_full Flows and fates of nickel-cadmium batteries in the City of Cape Town
title_fullStr Flows and fates of nickel-cadmium batteries in the City of Cape Town
title_full_unstemmed Flows and fates of nickel-cadmium batteries in the City of Cape Town
title_short Flows and fates of nickel-cadmium batteries in the City of Cape Town
title_sort flows and fates of nickel cadmium batteries in the city of cape town
topic Chemical Engineering
url http://hdl.handle.net/11427/14810
work_keys_str_mv AT masonjoneskyle flowsandfatesofnickelcadmiumbatteriesinthecityofcapetown