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The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands

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Main Author: Soldenhoff, Karin
Other Authors: Preston, J S
Format: Thesis
Language:English
Published: Centre for Minerals Research 2016
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access_status_str Open Access
author Soldenhoff, Karin
author2 Preston, J S
author_browse Preston, J S
Soldenhoff, Karin
author_facet Preston, J S
Soldenhoff, Karin
author_sort Soldenhoff, Karin
collection Thesis
description Summary in English.
format Thesis
id oai:open.uct.ac.za:11427/16408
institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:36:50.335Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2016
publishDateRange 2016
publishDateSort 2016
publisher Centre for Minerals Research
publisherStr Centre for Minerals Research
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/16408 The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands Soldenhoff, Karin Preston, J S Orren, M J Koch, K Chemical Engineering Minerals Research Summary in English. Bibliography: pages 96-100. The extraction of copper from chloride solutions with some aliphatic oximes as well as some pyridine carboxylates was studied and the complexes formed in the organic phase identified. The association of octanal oxime in toluene was taken into account in the extraction studies and formation constants for dimers and trimers obtained. Copper (II), Nickel (II) and Cobalt (II) are extracted by a solvating mechanism in which only the neutral MCl2 species is extractable. This reaction is largely independent of pH. Studies were also carried out on the use of the commercial reagent ACORGA CLX-20, for the selective extraction of copper from a synthetic solution simulating leach liquors obtained by ferric chloride leaching of complex sulphide ores. Results show that separation of copper from iron is dependent on the amount of acid and chloride present in the aqueous phase. 2016-01-15T14:19:13Z 2016-01-15T14:19:13Z 1986 Master Thesis Masters MSc http://hdl.handle.net/11427/16408 eng application/pdf Centre for Minerals Research Faculty of Engineering and the Built Environment University of Cape Town
spellingShingle Chemical Engineering
Minerals Research
Soldenhoff, Karin
The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
thesis_degree_str Master's
title The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
title_full The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
title_fullStr The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
title_full_unstemmed The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
title_short The solvent extraction of CU (II) from chloride solutions with certain non-chelating nitrogen donor ligands
title_sort solvent extraction of cu ii from chloride solutions with certain non chelating nitrogen donor ligands
topic Chemical Engineering
Minerals Research
url http://hdl.handle.net/11427/16408
work_keys_str_mv AT soldenhoffkarin thesolventextractionofcuiifromchloridesolutionswithcertainnonchelatingnitrogendonorligands
AT soldenhoffkarin solventextractionofcuiifromchloridesolutionswithcertainnonchelatingnitrogendonorligands