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Aqueous phase catalysis using mono- and bimetallic transition metal complexes
Includes bibliographical references
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
Department of Chemistry
2016
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| _version_ | 1867614277898076160 |
|---|---|
| access_status_str | Open Access |
| author | Matsinha, Leah Charlie |
| author2 | Smith, Gregory S |
| author_browse | Matsinha, Leah Charlie Smith, Gregory S |
| author_facet | Smith, Gregory S Matsinha, Leah Charlie |
| author_sort | Matsinha, Leah Charlie |
| collection | Thesis |
| description | Includes bibliographical references |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/16704 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:49:29.785Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/16704 Aqueous phase catalysis using mono- and bimetallic transition metal complexes Matsinha, Leah Charlie Smith, Gregory S Mapolie, Selwyn F Venter, Gerhard A Chemistry Includes bibliographical references The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. All the complexes were characterized using nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crystal X-ray diffraction (for complex 2.14), mass spectrometry, elemental analysis and melting point determinations. 2016-02-02T14:43:55Z 2016-02-02T14:43:55Z 2015 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/16704 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Matsinha, Leah Charlie Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| thesis_degree_str | Doctoral |
| title | Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| title_full | Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| title_fullStr | Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| title_full_unstemmed | Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| title_short | Aqueous phase catalysis using mono- and bimetallic transition metal complexes |
| title_sort | aqueous phase catalysis using mono and bimetallic transition metal complexes |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/16704 |
| work_keys_str_mv | AT matsinhaleahcharlie aqueousphasecatalysisusingmonoandbimetallictransitionmetalcomplexes |