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Conformational studies of some small biological molecules and their interactions with metal ions
The solid Cu(II) and Co(II) complexes and complex salts of some thiamine analogues have been prepared. Their electronic spectra, I.R. spectra and Magnetic Moments are presented and discussed in terms of suggested coordination geometries for the complexes. In addition the solution conformations of th...
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867613660823683072 |
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| access_status_str | Open Access |
| author | Russell, Jill Catherine |
| author2 | Fazakerley, G V |
| author_browse | Fazakerley, G V Russell, Jill Catherine |
| author_facet | Fazakerley, G V Russell, Jill Catherine |
| author_sort | Russell, Jill Catherine |
| collection | Thesis |
| description | The solid Cu(II) and Co(II) complexes and complex salts of some thiamine analogues have been prepared. Their electronic spectra, I.R. spectra and Magnetic Moments are presented and discussed in terms of suggested coordination geometries for the complexes. In addition the solution conformations of the Gd(III), Dy(III) and Ho (III) complexes of some 3' , 5' cyclic nucleotides were determined quantitatively using NMR line broadening and line shifting techniques. Reactions of Mn(II) with the cyclic nucleotides were used to find the preferred binding sites on the ligands also using line broadening techniques. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/16771 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:39:41.297Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/16771 Conformational studies of some small biological molecules and their interactions with metal ions Russell, Jill Catherine Fazakerley, G V Chemistry The solid Cu(II) and Co(II) complexes and complex salts of some thiamine analogues have been prepared. Their electronic spectra, I.R. spectra and Magnetic Moments are presented and discussed in terms of suggested coordination geometries for the complexes. In addition the solution conformations of the Gd(III), Dy(III) and Ho (III) complexes of some 3' , 5' cyclic nucleotides were determined quantitatively using NMR line broadening and line shifting techniques. Reactions of Mn(II) with the cyclic nucleotides were used to find the preferred binding sites on the ligands also using line broadening techniques. 2016-02-05T07:12:25Z 2016-02-05T07:12:25Z 1976 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/16771 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Russell, Jill Catherine Conformational studies of some small biological molecules and their interactions with metal ions |
| thesis_degree_str | Doctoral |
| title | Conformational studies of some small biological molecules and their interactions with metal ions |
| title_full | Conformational studies of some small biological molecules and their interactions with metal ions |
| title_fullStr | Conformational studies of some small biological molecules and their interactions with metal ions |
| title_full_unstemmed | Conformational studies of some small biological molecules and their interactions with metal ions |
| title_short | Conformational studies of some small biological molecules and their interactions with metal ions |
| title_sort | conformational studies of some small biological molecules and their interactions with metal ions |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/16771 |
| work_keys_str_mv | AT russelljillcatherine conformationalstudiesofsomesmallbiologicalmoleculesandtheirinteractionswithmetalions |