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Investigation of the effect of the reagent suite in froth flotation of a Merensky ore

The mining industry is faced with a challenge to develop efficient and economically feasible processing routes owing to the depletion of high-grade ores, and the ever increasing demand for precious metals for a wide range of applications. The valuable minerals, PGMs (Platinum Group Minerals) and BMS...

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Main Author: Moimane, Tiisetso Makheane
Other Authors: Corin, Kirsten
Format: Thesis
Language:English
Published: Department of Chemical Engineering 2016
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access_status_str Open Access
author Moimane, Tiisetso Makheane
author2 Corin, Kirsten
author_browse Corin, Kirsten
Moimane, Tiisetso Makheane
author_facet Corin, Kirsten
Moimane, Tiisetso Makheane
author_sort Moimane, Tiisetso Makheane
collection Thesis
description The mining industry is faced with a challenge to develop efficient and economically feasible processing routes owing to the depletion of high-grade ores, and the ever increasing demand for precious metals for a wide range of applications. The valuable minerals, PGMs (Platinum Group Minerals) and BMS (Base Metal Sulphides) in the ores are extracted through the aid of chemical reagents (activators, collectors, depressants, frothers, modifiers) which are added to the flotation circuits to facilitate the separation between these minerals and the undesired gangue minerals present in the ore. The process is made complex by many surface reactions taking place, the existence of secondary and interactive effects among the flotation reagents, as well as the surface liberation of the minerals. Owing to the stringent regulations around water usage, concentrator plants are left with no option but to recycle water within their operations. This practice leads to accumulation of pollutants, such as organics, flotation reagents residues, dissolved ions, etc., which will likely have an influence on the chemical environment of the process, and subsequently will bear an impact on the overall metallurgical performance of the concentrator. This makes the process even more intricate, making it difficult to account for the behaviour of the chemical reagents, as well as making it virtually impossible to precisely assess their individual contribution to the overall flotation performance. Hence it is of crucial importance to adopt a holistic approach when investigating the effects of the chemical parameters in a flotation process. This is a flotation chemistry study that adopted a two-level-four-factor (24) factorial experimental design to evaluate the simultaneous effects of the chemical parameters, with particular reference to collector, depressant, frother, and ionic strength of the synthetic plant water, as well as determining the possible interactive effects between the chosen parameters. This investigation was made possible by conducting batch flotation tests on a PGM-bearing ore from the Merensky reef of the Bushveld Igneous Complex. Sodium isobutyl xanthate (SIBX), a polysaccharide, namely guar gum, and a polyglycol ether, namely Dowfroth 250 were used as the collector, depressant and frother, respectively. These are the typical chemical reagents the dosages of which tailored in the PGM industry for the processing of the ores. The metallurgical performance indicators used were solids, water, copper and nickel recoveries as well as copper and nickel grades.
format Thesis
id oai:open.uct.ac.za:11427/20088
institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:40:18.241Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2016
publishDateRange 2016
publishDateSort 2016
publisher Department of Chemical Engineering
publisherStr Department of Chemical Engineering
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/20088 Investigation of the effect of the reagent suite in froth flotation of a Merensky ore Moimane, Tiisetso Makheane Corin, Kirsten Wiese, Jenny Chemical Engineering The mining industry is faced with a challenge to develop efficient and economically feasible processing routes owing to the depletion of high-grade ores, and the ever increasing demand for precious metals for a wide range of applications. The valuable minerals, PGMs (Platinum Group Minerals) and BMS (Base Metal Sulphides) in the ores are extracted through the aid of chemical reagents (activators, collectors, depressants, frothers, modifiers) which are added to the flotation circuits to facilitate the separation between these minerals and the undesired gangue minerals present in the ore. The process is made complex by many surface reactions taking place, the existence of secondary and interactive effects among the flotation reagents, as well as the surface liberation of the minerals. Owing to the stringent regulations around water usage, concentrator plants are left with no option but to recycle water within their operations. This practice leads to accumulation of pollutants, such as organics, flotation reagents residues, dissolved ions, etc., which will likely have an influence on the chemical environment of the process, and subsequently will bear an impact on the overall metallurgical performance of the concentrator. This makes the process even more intricate, making it difficult to account for the behaviour of the chemical reagents, as well as making it virtually impossible to precisely assess their individual contribution to the overall flotation performance. Hence it is of crucial importance to adopt a holistic approach when investigating the effects of the chemical parameters in a flotation process. This is a flotation chemistry study that adopted a two-level-four-factor (24) factorial experimental design to evaluate the simultaneous effects of the chemical parameters, with particular reference to collector, depressant, frother, and ionic strength of the synthetic plant water, as well as determining the possible interactive effects between the chosen parameters. This investigation was made possible by conducting batch flotation tests on a PGM-bearing ore from the Merensky reef of the Bushveld Igneous Complex. Sodium isobutyl xanthate (SIBX), a polysaccharide, namely guar gum, and a polyglycol ether, namely Dowfroth 250 were used as the collector, depressant and frother, respectively. These are the typical chemical reagents the dosages of which tailored in the PGM industry for the processing of the ores. The metallurgical performance indicators used were solids, water, copper and nickel recoveries as well as copper and nickel grades. 2016-06-22T08:57:49Z 2016-06-22T08:57:49Z 2015 Master Thesis Masters MSc (Eng) http://hdl.handle.net/11427/20088 eng application/pdf Department of Chemical Engineering Faculty of Engineering and the Built Environment University of Cape Town
spellingShingle Chemical Engineering
Moimane, Tiisetso Makheane
Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
thesis_degree_str Master's
title Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
title_full Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
title_fullStr Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
title_full_unstemmed Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
title_short Investigation of the effect of the reagent suite in froth flotation of a Merensky ore
title_sort investigation of the effect of the reagent suite in froth flotation of a merensky ore
topic Chemical Engineering
url http://hdl.handle.net/11427/20088
work_keys_str_mv AT moimanetiisetsomakheane investigationoftheeffectofthereagentsuiteinfrothflotationofamerenskyore