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The synthesis and host-guest activity of novel cyanoborate salts
Molecular recognition is a dynamic process based on distinct chemical interactions and not on passive fitting of a lock and key. Complex formation between host and guest molecules is often accompanied by conformational reorganisation, which makes it possible to engineer and fine-tune synthetic recep...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867611349959311360 |
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| access_status_str | Open Access |
| author | Haueisen, Renate H |
| author2 | Hunter, Roger |
| author_browse | Haueisen, Renate H Hunter, Roger |
| author_facet | Hunter, Roger Haueisen, Renate H |
| author_sort | Haueisen, Renate H |
| collection | Thesis |
| description | Molecular recognition is a dynamic process based on distinct chemical interactions and not on passive fitting of a lock and key. Complex formation between host and guest molecules is often accompanied by conformational reorganisation, which makes it possible to engineer and fine-tune synthetic receptor analogues for optimal function and selectivity. This thesis primarily describes a supramolecular study of a novel family of airstable cyanoborate host compounds. The discovery of this clathrand family came about as a result of a study relating to the synthesis of an electrolyte for the Zebra car battery and the thesis begins with this aspect (Chapter 1). Although cyanoborates are well documented as synthetic intermediates in 1,2 migration reactions they have not been studied independently to any degree and this thesis constitutes the first significant study of this class of compound. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/21429 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/21429 The synthesis and host-guest activity of novel cyanoborate salts Haueisen, Renate H Hunter, Roger Chemistry Molecular recognition is a dynamic process based on distinct chemical interactions and not on passive fitting of a lock and key. Complex formation between host and guest molecules is often accompanied by conformational reorganisation, which makes it possible to engineer and fine-tune synthetic receptor analogues for optimal function and selectivity. This thesis primarily describes a supramolecular study of a novel family of airstable cyanoborate host compounds. The discovery of this clathrand family came about as a result of a study relating to the synthesis of an electrolyte for the Zebra car battery and the thesis begins with this aspect (Chapter 1). Although cyanoborates are well documented as synthetic intermediates in 1,2 migration reactions they have not been studied independently to any degree and this thesis constitutes the first significant study of this class of compound. 2016-08-22T12:26:15Z 2016-08-22T12:26:15Z 1994 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/21429 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Haueisen, Renate H The synthesis and host-guest activity of novel cyanoborate salts |
| thesis_degree_str | Doctoral |
| title | The synthesis and host-guest activity of novel cyanoborate salts |
| title_full | The synthesis and host-guest activity of novel cyanoborate salts |
| title_fullStr | The synthesis and host-guest activity of novel cyanoborate salts |
| title_full_unstemmed | The synthesis and host-guest activity of novel cyanoborate salts |
| title_short | The synthesis and host-guest activity of novel cyanoborate salts |
| title_sort | synthesis and host guest activity of novel cyanoborate salts |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/21429 |
| work_keys_str_mv | AT haueisenrenateh thesynthesisandhostguestactivityofnovelcyanoboratesalts AT haueisenrenateh synthesisandhostguestactivityofnovelcyanoboratesalts |