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Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt
The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, in...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867613202899009537 |
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| access_status_str | Open Access |
| author | Finch, Karol Paula |
| author2 | Moss, John R |
| author_browse | Finch, Karol Paula Moss, John R |
| author_facet | Moss, John R Finch, Karol Paula |
| author_sort | Finch, Karol Paula |
| collection | Thesis |
| description | The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/21938 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:32:24.523Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/21938 Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt Finch, Karol Paula Moss, John R Jackson, Graham Ellis Fischer-Tropsch process Chemistry The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques. 2016-09-25T16:52:20Z 2016-09-25T16:52:20Z 1988 Master Thesis Masters MSc http://hdl.handle.net/11427/21938 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Fischer-Tropsch process Chemistry Finch, Karol Paula Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| thesis_degree_str | Master's |
| title | Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| title_full | Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| title_fullStr | Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| title_full_unstemmed | Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| title_short | Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt |
| title_sort | synthesis characterisation and reactivity studies of μ α ω alkanediyl complexes of ruthenium iron and cobalt |
| topic | Fischer-Tropsch process Chemistry |
| url | http://hdl.handle.net/11427/21938 |
| work_keys_str_mv | AT finchkarolpaula synthesischaracterisationandreactivitystudiesofmaōalkanediylcomplexesofrutheniumironandcobalt |