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Stereoselective synthesis of perhydrobenzo[4.5.6]cholestanes
An intramolecular Michael-aldol reaction sequence has been developed for the stereocontrolled synthesis of pentacyclic steroids! with the new six-membered ring attached to the C(4) and C(6) positions. Cholesterol was converted into 3β-hydroxycholest-4-en-6-one by standard methods, and the correspond...
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| Language: | English |
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Department of Chemistry
2016
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