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Transition metal complexes of bis(diphenylphosphino)methane, dithizone and dithiolenes: structural, spectroscopic, electrochemical and computational studies
A series of heterobi- and tri-metallic complexes were prepared by the metallation of the carbanion derived from [M(CO)₄(dppm)] (M = Cr, Mo or W), [ML(dppm)] (L= dithiolene; M = Pd or Pt), or the cationic precursor, [Ru(Cp)(PPh3)(dppm)]PF₆. The complexes were characterized by ¹H and ³¹P NMR, IR and U...
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| Language: | English |
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Department of Chemistry
2016
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