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Synthetic and structural studies on early transition metal siloxides

[Super- and subscripts in abstract] n-Bu3SiOH was prepared from both n-Bu3SiH and n-Bu3SiCI. Reactions of n-Bu3SiOH with NaH, LiBun, MC15 (M = Ta or Mo) and Cp2MCl2 (Cp = 115-C5H5, M = Ti or Zr) were investigated, in some cases using the base Et3N as a hydrogen chloride acceptor. Na+(QSiPh3r was pre...

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Bibliographic Details
Main Author: Jones, Robert Edward
Other Authors: Hutton, Alan T
Format: Thesis
Language:English
Published: Department of Chemistry 2017
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