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Selective criteria in Werner clathrates
We have elucidated the structures of a series of Werner Clathrates with systematically changing guest molecules. The host is the inorganic coordination compound bis(isothiocyanato)tetra(4-vinylpyridine)nickel(II), [Ni(NCS)2(4-ViPy)4]. The guests are mixtures of tetrahydrofuran and the cyclic hydroca...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2017
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| _version_ | 1867613379806363648 |
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| access_status_str | Open Access |
| author | Lavelle, Laurence |
| author_browse | Lavelle, Laurence |
| author_facet | Lavelle, Laurence |
| author_sort | Lavelle, Laurence |
| collection | Thesis |
| description | We have elucidated the structures of a series of Werner Clathrates with systematically changing guest molecules. The host is the inorganic coordination compound bis(isothiocyanato)tetra(4-vinylpyridine)nickel(II), [Ni(NCS)2(4-ViPy)4]. The guests are mixtures of tetrahydrofuran and the cyclic hydrocarbons: cyclohexane, cyclohexene, 1,3-cYclohexadiene, 1,4-cyclohexadiene and benzene. Host to guest ratios were elucidated by density and proton nuclear magnetic resonance spectroscopy. The thermal characteristics of the compounds were analysed by thermogravimetric analysis and differen.tial thermal analysis. The structures of two related compounds [Ni(NCS)2(Py)4] and [Ni(NCS)2(Py)4].nbenzene were also studied. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/23608 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:35:13.298Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2017 |
| publishDateRange | 2017 |
| publishDateSort | 2017 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/23608 Selective criteria in Werner clathrates Lavelle, Laurence Clathrate compounds We have elucidated the structures of a series of Werner Clathrates with systematically changing guest molecules. The host is the inorganic coordination compound bis(isothiocyanato)tetra(4-vinylpyridine)nickel(II), [Ni(NCS)2(4-ViPy)4]. The guests are mixtures of tetrahydrofuran and the cyclic hydrocarbons: cyclohexane, cyclohexene, 1,3-cYclohexadiene, 1,4-cyclohexadiene and benzene. Host to guest ratios were elucidated by density and proton nuclear magnetic resonance spectroscopy. The thermal characteristics of the compounds were analysed by thermogravimetric analysis and differen.tial thermal analysis. The structures of two related compounds [Ni(NCS)2(Py)4] and [Ni(NCS)2(Py)4].nbenzene were also studied. 2017-01-27T08:36:32Z 2017-01-27T08:36:32Z 1988 2016-12-06T11:23:45Z Thesis Masters MSc http://hdl.handle.net/11427/23608 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Clathrate compounds Lavelle, Laurence Selective criteria in Werner clathrates |
| thesis_degree_str | Master's |
| title | Selective criteria in Werner clathrates |
| title_full | Selective criteria in Werner clathrates |
| title_fullStr | Selective criteria in Werner clathrates |
| title_full_unstemmed | Selective criteria in Werner clathrates |
| title_short | Selective criteria in Werner clathrates |
| title_sort | selective criteria in werner clathrates |
| topic | Clathrate compounds |
| url | http://hdl.handle.net/11427/23608 |
| work_keys_str_mv | AT lavellelaurence selectivecriteriainwernerclathrates |