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Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models

Over the past 40 years, there has been a continuous progression in generating concrete solutions in the design and operation of wastewater treatment systems. This progression has included the development of various integrated and logical-mathematical glass box models geared towards the recovery of r...

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Main Author: Gaszynski, Christopher
Other Authors: Ekama, George
Format: Thesis
Language:English
Published: Department of Civil Engineering 2021
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access_status_str Open Access
author Gaszynski, Christopher
author2 Ekama, George
author_browse Ekama, George
Gaszynski, Christopher
author_facet Ekama, George
Gaszynski, Christopher
author_sort Gaszynski, Christopher
collection Thesis
description Over the past 40 years, there has been a continuous progression in generating concrete solutions in the design and operation of wastewater treatment systems. This progression has included the development of various integrated and logical-mathematical glass box models geared towards the recovery of resources. However, the accuracy of these models relies on characterising the influent waste stream accurately, which includes identifying the molecular composition of the biodegradable organics. Municipal wastewater contains an array of organics, and it is crucial to accurately identify the composition of these organics before they are fed into the virtually replicated (i.e. modelled) system. This identification of influent organics ensures that the performance of the system can be predicted, and system upset, or failure can be avoided. The overarching aim of this project was to characterise the composition of the organics present in municipal wastewater using experimental analysis and mathematical bioprocess modelling. The project extended and improved current analytical methods by developing: 1. The Augmented Biochemical Methane Potential (AugBMP) Test: A test run identically to the BMP test but extended to include the methane and carbon dioxide production, the aqueous phase volatile fatty acids (VFAs), H2CO3 and total alkalinity, ammonia and orthophosphate concentrations and the reactor pH. 2. The Augmented Biochemical Sulphide Potential (AugBSP) Test: A test aimed to improve the accuracy of the AugBMP test, as methanogenesis was replaced by Biological Sulphate Reduction (BSR), minimising the gas measurement error commonly experienced during the BMP test. The proposed AugBMP and AugBSP tests coupled with mathematical bioprocess modelling, provides a powerful tool for determining the composition of the biodegradable organics present in wastewater substrates. The project incorporated a holistic approach which included fabricating the proposed testing vessels, performing multiple experiments and as accurately as possible, simulating the observed outcome using mathematical models. The outcome of this project allowed for the composition of unknown substrates, such as the organics present in primary sewage sludge to be identified confidently. This thesis unpacks and describes this new methodology developed to characterise substrates with unknown composition.
format Thesis
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institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:43:03.561Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2021
publishDateRange 2021
publishDateSort 2021
publisher Department of Civil Engineering
publisherStr Department of Civil Engineering
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source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/33787 Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models Gaszynski, Christopher Ekama, George Ikumi, David Civil Engineering Over the past 40 years, there has been a continuous progression in generating concrete solutions in the design and operation of wastewater treatment systems. This progression has included the development of various integrated and logical-mathematical glass box models geared towards the recovery of resources. However, the accuracy of these models relies on characterising the influent waste stream accurately, which includes identifying the molecular composition of the biodegradable organics. Municipal wastewater contains an array of organics, and it is crucial to accurately identify the composition of these organics before they are fed into the virtually replicated (i.e. modelled) system. This identification of influent organics ensures that the performance of the system can be predicted, and system upset, or failure can be avoided. The overarching aim of this project was to characterise the composition of the organics present in municipal wastewater using experimental analysis and mathematical bioprocess modelling. The project extended and improved current analytical methods by developing: 1. The Augmented Biochemical Methane Potential (AugBMP) Test: A test run identically to the BMP test but extended to include the methane and carbon dioxide production, the aqueous phase volatile fatty acids (VFAs), H2CO3 and total alkalinity, ammonia and orthophosphate concentrations and the reactor pH. 2. The Augmented Biochemical Sulphide Potential (AugBSP) Test: A test aimed to improve the accuracy of the AugBMP test, as methanogenesis was replaced by Biological Sulphate Reduction (BSR), minimising the gas measurement error commonly experienced during the BMP test. The proposed AugBMP and AugBSP tests coupled with mathematical bioprocess modelling, provides a powerful tool for determining the composition of the biodegradable organics present in wastewater substrates. The project incorporated a holistic approach which included fabricating the proposed testing vessels, performing multiple experiments and as accurately as possible, simulating the observed outcome using mathematical models. The outcome of this project allowed for the composition of unknown substrates, such as the organics present in primary sewage sludge to be identified confidently. This thesis unpacks and describes this new methodology developed to characterise substrates with unknown composition. 2021-08-17T10:11:33Z 2021-08-17T10:11:33Z 2021 2021-08-10T09:31:44Z Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/33787 eng application/pdf Department of Civil Engineering Faculty of Engineering and the Built Environment
spellingShingle Civil Engineering
Gaszynski, Christopher
Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
thesis_degree_str Doctoral
title Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
title_full Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
title_fullStr Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
title_full_unstemmed Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
title_short Identification of Wastewater Primary Sludge Composition using Augmented Batch Tests and Mathematical Models
title_sort identification of wastewater primary sludge composition using augmented batch tests and mathematical models
topic Civil Engineering
url http://hdl.handle.net/11427/33787
work_keys_str_mv AT gaszynskichristopher identificationofwastewaterprimarysludgecompositionusingaugmentedbatchtestsandmathematicalmodels