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The synthesis and characterization of novel rhodium alkenyl complexes and rhodacycloalkanes
The rhodium dimers [Cp*RhChh and [Cp*RhBr2h were reacted with alkenyl Grignard reagents MgBr(CH2)nCH=CH2 (n = 1 - 4, 6, 8, 9) in an attempt to form bis-alkenyl complexes that would be potential precursors to rhodium-containing metallacycloalkanes. The shorter-chain Grignard reagents (n = 1 - 3) prod...
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| Language: | English |
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Department of Chemistry
2024
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