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Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)
Includes bibliographical references.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2014
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| _version_ | 1867613286957056000 |
|---|---|
| access_status_str | Open Access |
| author | Hallale, Oren |
| author2 | Bourne, Susan A |
| author_browse | Bourne, Susan A Hallale, Oren |
| author_facet | Bourne, Susan A Hallale, Oren |
| author_sort | Hallale, Oren |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/6310 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:33:43.673Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2014 |
| publishDateRange | 2014 |
| publishDateSort | 2014 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/6310 Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) Hallale, Oren Bourne, Susan A Koch, Klaus Chemistry Includes bibliographical references. Rationally designed bipodal3,3,3',3'-tetraalkyl-l,1'-benzoylbis(thioureas) are used as pre-programmed cheiating ligands to form metallamacrocyclic square planar nickel(ll) complexes via self-assembly. Metal : ligand stoichiometries of either 2:2 or 3:3 can be achieved by using meta- or para- substituted ligands. The metallamacrocyclic complexes are subsequently converted into octahedral adducts via the addition of monodentate nitrogen donor ligands. Metallamacrocycles are further employed as secondary building units in the self-assembly of I-dimensional double- or tripleconnected coordination polymers. The synthesis of these polymers is achieved with the use of exo-bidentate nitrogen donor ligands. 2014-08-13T14:26:24Z 2014-08-13T14:26:24Z 2004 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/6310 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Hallale, Oren Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| thesis_degree_str | Doctoral |
| title | Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| title_full | Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| title_fullStr | Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| title_full_unstemmed | Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| title_short | Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) |
| title_sort | progressive design and self assembly of supramolecular architectures based on metallamacrocyclic nickel ii complexes with bipodal tetra alkylaroylbis thioureas |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/6310 |
| work_keys_str_mv | AT hallaleoren progressivedesignandselfassemblyofsupramoleculararchitecturesbasedonmetallamacrocyclicnickeliicomplexeswithbipodaltetraalkylaroylbisthioureas |