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Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II)
Includes bibliographical references.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2014
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| _version_ | 1867613337154486272 |
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| access_status_str | Open Access |
| author | Miller, Jörn Derrick Schuster |
| author2 | Koch, Klaus |
| author_browse | Koch, Klaus Miller, Jörn Derrick Schuster |
| author_facet | Koch, Klaus Miller, Jörn Derrick Schuster |
| author_sort | Miller, Jörn Derrick Schuster |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/6336 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:34:32.198Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2014 |
| publishDateRange | 2014 |
| publishDateSort | 2014 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/6336 Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) Miller, Jörn Derrick Schuster Koch, Klaus Chemistry Includes bibliographical references. The synthesis of simple, and also bipodal N-substituted N'-acyl- and N'-aroylthiourea ligands has been investigated, along with aspects of their co-ordination chemistry to Pt(II) and Pd(II). The ligands are commonly produced by reacting a secondary or primary amine with an acyl or aroyl isothiocyanate. This synthesis requires nucleophilic addition of the amine to the thiocarbonyl carbon of the acyl or aroyl isothocyanate. However, a competitive side-reaction frequently occurs because the amine nucleophile can attack the carbonyl carbon of the isothiocyanate reagent instead. This leads to substitution of the isothiocyanate moiety and the formation of an N-substituted amide. 2014-08-13T14:27:14Z 2014-08-13T14:27:14Z 2000 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/6336 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Miller, Jörn Derrick Schuster Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| thesis_degree_str | Doctoral |
| title | Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| title_full | Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| title_fullStr | Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| title_full_unstemmed | Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| title_short | Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) |
| title_sort | synthesis of n alkyl and n n dialkyl n acyl and n aroythioureas and aspects of their co ordination chemistry with pt ii and pd ii |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/6336 |
| work_keys_str_mv | AT millerjornderrickschuster synthesisofnalkylandnndialkylnacylandnaroythioureasandaspectsoftheircoordinationchemistrywithptiiandpdii |