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Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance
Includes bibliography.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
Department of Chemistry
2014
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| _version_ | 1867613214489968640 |
|---|---|
| access_status_str | Open Access |
| author | Hill, Robert Oliver |
| author2 | Moss, John R |
| author_browse | Hill, Robert Oliver Moss, John R |
| author_facet | Moss, John R Hill, Robert Oliver |
| author_sort | Hill, Robert Oliver |
| collection | Thesis |
| description | Includes bibliography. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/9772 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:32:34.479Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2014 |
| publishDateRange | 2014 |
| publishDateSort | 2014 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/9772 Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance Hill, Robert Oliver Moss, John R Marias, Charles Naidoo, Kevin J Chemistry Includes bibliography. The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described. 2014-11-21T16:15:23Z 2014-11-21T16:15:23Z 1999 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/9772 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Hill, Robert Oliver Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| thesis_degree_str | Doctoral |
| title | Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| title_full | Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| title_fullStr | Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| title_full_unstemmed | Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| title_short | Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance |
| title_sort | synthetic structural and molecular modelling studies of organoiron complexes of catalytic importance |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/9772 |
| work_keys_str_mv | AT hillrobertoliver syntheticstructuralandmolecularmodellingstudiesoforganoironcomplexesofcatalyticimportance |