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Inclusion compounds : structure, reactivity and selectivity
Includes bibliographical references.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
Department of Chemistry
2014
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| _version_ | 1867614503758200832 |
|---|---|
| access_status_str | Open Access |
| author | Su, Hong |
| author2 | Nassimbeni, Luigi R |
| author_browse | Nassimbeni, Luigi R Su, Hong |
| author_facet | Nassimbeni, Luigi R Su, Hong |
| author_sort | Su, Hong |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/9783 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:53:05.182Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2014 |
| publishDateRange | 2014 |
| publishDateSort | 2014 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/9783 Inclusion compounds : structure, reactivity and selectivity Su, Hong Nassimbeni, Luigi R Chemistry Includes bibliographical references. This thesis is concerned with structure, thermodynamic and kinetic aspects of a variety of inclusion compounds which contain small organic guests. The host compounds studied are alkaline-earth metal salts of O,O’-dibenzoyl-(2R, 3R)-tartraric acid (magnesium, calcium and strontium), 1,1’-bis-(4-hydroxyphenyl)cyclohexane (DHPC) and 2,2’-dihydroxy-1,1’-binaphthyl (BINAP). The alkaline-earth metal salts form coordination complexes with 2-methoxyethanol, water or ethanol and the guests act as a part of the coordination sphere of the metal ions. The diol host DHPC preferably forms layer type inclusion compounds with the isomers of picoline, lutidine and xylidine, as well as a number of selected solvents including 1,4-dioxane, DMSO, morpholine, THF and acetone, preferably in channel type inclusion modes. In the latter two classes of inclusion compounds the inclusion is facilitated by the formation of hydrogen bonds from the host hydroxyl moieties to the guests. 2014-11-22T05:52:53Z 2014-11-22T05:52:53Z 2002 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/9783 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Su, Hong Inclusion compounds : structure, reactivity and selectivity |
| thesis_degree_str | Doctoral |
| title | Inclusion compounds : structure, reactivity and selectivity |
| title_full | Inclusion compounds : structure, reactivity and selectivity |
| title_fullStr | Inclusion compounds : structure, reactivity and selectivity |
| title_full_unstemmed | Inclusion compounds : structure, reactivity and selectivity |
| title_short | Inclusion compounds : structure, reactivity and selectivity |
| title_sort | inclusion compounds structure reactivity and selectivity |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/9783 |
| work_keys_str_mv | AT suhong inclusioncompoundsstructurereactivityandselectivity |