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Estimation of the refractive indices of some binary mixtures

Refractive index is a useful fluid characterization parameter with widespread industrial applications. The values for many pure liquids are known or readily available in literature. However, when experimental data are not available, the refractive indices of binary and multi-component liquids are of...

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Published: 2015
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LEADER 00000njm a2000000a 4500
001 oai:repository.ui.edu.ng:123456789/13766
042 |a dc 
720 |a Isehunwa, S. O.  |e author 
720 |a Olanisebe, E. B.  |e author 
720 |a Ajiboye, O. O.  |e author 
720 |a Akintola, S. A.  |e author 
260 |c 2015 
520 |a Refractive index is a useful fluid characterization parameter with widespread industrial applications. The values for many pure liquids are known or readily available in literature. However, when experimental data are not available, the refractive indices of binary and multi-component liquids are often estimated from the pure components using mixing rules which are sometimes not accurate. This study was designed to measure the refractive indices and evaluate the accuracy of some commonly used mixing rules when applied to benzene-toluene, heptane-hexane, hexane-acetone, heptane-acetic acid and acetic acid-acetone binary mixtures at varying volume fractions and temperatures between 20 and 60°C. A simpler relation based on modified Kay or Arago-Biot mixing rule was demonstrated to have wider range of applicability because of the explicit temperature-dependence term. 
024 8 |a 1996 - 0840 
024 8 |a ui_art_isehunwa_estimation_2015. 
024 8 |a African Journal of Pure and Applied Chemistry 10 (4), pp. 58-64 
024 8 |a https://repository.ui.edu.ng/handle/123456789/13766 
653 |a Refractive index 
653 |a mixing rule 
653 |a binary mixtures 
653 |a excess volume 
653 |a refractometer 
245 0 0 |a Estimation of the refractive indices of some binary mixtures