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The influence of salts in carrier water and adjuvants on glyphosate activity

Thesis (PhD (Agronomy))--University of Pretoria, 2005.

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Other Authors: Reinhardt, Carl Frederick (Charlie)
Format: Thesis
Published: University of Pretoria 2013
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access_status_str Open Access
author2 Reinhardt, Carl Frederick (Charlie)
author_browse Reinhardt, Carl Frederick (Charlie)
author_facet Reinhardt, Carl Frederick (Charlie)
collection Thesis
dc_rights_str_mv © 2002 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria.
description Thesis (PhD (Agronomy))--University of Pretoria, 2005.
format Thesis
id oai:repository.up.ac.za:2263/28584
institution University of Pretoria (South Africa)
last_indexed 2026-06-10T12:39:12.360Z
license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository
publishDate 2013
publishDateRange 2013
publishDateSort 2013
publisher University of Pretoria
publisherStr University of Pretoria
record_format dspace
source_str UPSpace — University of Pretoria Institutional Repository
spelling oai:repository.up.ac.za:2263/28584 The influence of salts in carrier water and adjuvants on glyphosate activity Reinhardt, Carl Frederick (Charlie) upetd@up.ac.za De Villiers, Brian Lindsay Agricultural chemicals adjuvants Glyphosate antagonists UCTD Thesis (PhD (Agronomy))--University of Pretoria, 2005. Glyphosate, a non-selective herbicide, is antagonized by salts in the spray carrier and responds to surfactant type and concentration. Glyphosate antagonism by dissolved salts such as calcium and magnesium was verified with natural water carriers and with carriers to which salts were added. Salt antagonism of glyphosate occurred from the formation of complexes that were less absorptive than the formulated isopropylamine glyphosate. Absorption of various salts of glyphosate varied as follows: isopropylamine > acid > ammonium > sodium > calcium. Ammonium sulphate increased the absorption of glyphosate both in distilled water carriers and in water carriers containing calcium chloride. Absorption and retention of glyphosate generally increased as surfactant (nonylphenol ethoxylate) hydrophilic/lipophilic balance (HLB) increased. The optimal HLB for glyphosate absorption was lower when ammonium sulphate was added to the spray carrier. An experimental adjuvant (trade name: Power-Up) that contained nonionic surfactant and ammonium sulphate, increased glyphosate efficacy more than the currently registered South African adjuvants. This could be as a result of increased foliar absorption and/or retention on foliage. The use of acid containing adjuvants was not essential for adequate glyphosate efficacy. Visual assessment of spray droplet residuals on leaves indicated that the appearance of spray droplet residuals was linked to glyphosate efficacy. Thick, amorphous and grainy spray droplet residuals on the leaf surface was an indicator of poor efficacy, whilst thinner, smoother residuals in close contact with the leaf surface was linked to increased efficacy. Plant Production and Soil Science unrestricted 2013-09-07T13:45:27Z 2005-10-11 2013-09-07T13:45:27Z 2002-08-01 2005-10-11 2005-10-10 Thesis De Villiers, BL 2002, The influence of salts in carrier water and adjuvants on glyphosate activity, PhD thesis, University of Pretoria, Pretoria, viewed yymmdd < http://hdl.handle.net/2263/28584 > H1148/ag http://hdl.handle.net/2263/28584 http://upetd.up.ac.za/thesis/available/etd-10102005-104826/ © 2002 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria
spellingShingle Agricultural chemicals adjuvants
Glyphosate antagonists
UCTD
The influence of salts in carrier water and adjuvants on glyphosate activity
title The influence of salts in carrier water and adjuvants on glyphosate activity
title_full The influence of salts in carrier water and adjuvants on glyphosate activity
title_fullStr The influence of salts in carrier water and adjuvants on glyphosate activity
title_full_unstemmed The influence of salts in carrier water and adjuvants on glyphosate activity
title_short The influence of salts in carrier water and adjuvants on glyphosate activity
title_sort influence of salts in carrier water and adjuvants on glyphosate activity
topic Agricultural chemicals adjuvants
Glyphosate antagonists
UCTD
url http://hdl.handle.net/2263/28584
http://upetd.up.ac.za/thesis/available/etd-10102005-104826/