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Effect of mould flux on scale adhesion to reheated stainless steel slabs

Dissertation (MSc)--University of Pretoria, 2009.

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Other Authors: Pistorius, Petrus Christiaan
Format: Thesis
Published: University of Pretoria 2013
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access_status_str Open Access
author2 Pistorius, Petrus Christiaan
author_browse Pistorius, Petrus Christiaan
author_facet Pistorius, Petrus Christiaan
collection Thesis
dc_rights_str_mv © 2008, University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria.
description Dissertation (MSc)--University of Pretoria, 2009.
format Thesis
id oai:repository.up.ac.za:2263/29840
institution University of Pretoria (South Africa)
last_indexed 2026-06-10T12:37:18.025Z
license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository
publishDate 2013
publishDateRange 2013
publishDateSort 2013
publisher University of Pretoria
publisherStr University of Pretoria
record_format dspace
source_str UPSpace — University of Pretoria Institutional Repository
spelling oai:repository.up.ac.za:2263/29840 Effect of mould flux on scale adhesion to reheated stainless steel slabs Pistorius, Petrus Christiaan jeanjacquesmukadi@yahoo.fr Ndiabintu, Mukadi Jean-Jacques Scale Chromite Tendrils of nickel-rich filigree Austenite grain boundaries Interfacial morphology Free oxygen Stainless steel Mould flux Reheating Hydraulic descaling Internal oxidation UCTD Dissertation (MSc)--University of Pretoria, 2009. Effects of mould flux contaminant on scale-steel adhesion and hydraulic descaling of scale formed on slabs were investigated. In this investigation, stainless steel type 304 (austenitic with 18% Cr and 8% Ni) and specific mould fluxes were used when growing the scale on contaminated samples under simulated industrial reheating conditions, with subsequent high pressure water hydraulic descaling. The basic hypothesis was that the steel-scale adhesion depends on the microstructure of different phases present in the scale, the segregation of specific elements at the interface and the interfacial morphology of the scale after reheating. It was found that mould flux contaminant decreases scale-steel adhesion and therefore improved the descaling effectiveness significantly compared to non contaminated stainless steel. The descaling effectiveness of contaminated and uncontaminated slab was dependent to the presence of metal free paths (chromite layers along the austenite grains boundaries) and the presence of unoxidized metal in the scale due to nickel enrichment at the interface. Compared to the uncontaminated samples, the descaling of contaminated samples was efficient which could be due to the fact that some mechanisms which increase scale– steel adhesion (notably nickel enrichment at the interface) were considerably reduced. For all contaminated samples, the descaling effectiveness after visual observation were close to 100% and it was found that mould flux type 832 ( low basicity) gave a high descaling efficiency with better steel surface quality after descaling compared to mould fluxes type 810 and RF1. Materials Science and Metallurgical Engineering unrestricted 2013-09-07T16:53:44Z 2009-12-09 2013-09-07T16:53:44Z 2009-09-02 2009-12-09 2009-11-26 Dissertation Ndiabintu, Mukadi, J-J 2008, Effect of mould flux on scale adhesion to reheated stainless steel slabs, MSc dissertation, University of Pretoria, Pretoria, viewed yymmdd < http://hdl.handle.net/2263/29840 > E1466/ag http://hdl.handle.net/2263/29840 http://upetd.up.ac.za/thesis/available/etd-11262009-192807/ © 2008, University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf University of Pretoria
spellingShingle Scale
Chromite
Tendrils of nickel-rich filigree
Austenite grain boundaries
Interfacial morphology
Free oxygen
Stainless steel
Mould flux
Reheating
Hydraulic descaling
Internal oxidation
UCTD
Effect of mould flux on scale adhesion to reheated stainless steel slabs
title Effect of mould flux on scale adhesion to reheated stainless steel slabs
title_full Effect of mould flux on scale adhesion to reheated stainless steel slabs
title_fullStr Effect of mould flux on scale adhesion to reheated stainless steel slabs
title_full_unstemmed Effect of mould flux on scale adhesion to reheated stainless steel slabs
title_short Effect of mould flux on scale adhesion to reheated stainless steel slabs
title_sort effect of mould flux on scale adhesion to reheated stainless steel slabs
topic Scale
Chromite
Tendrils of nickel-rich filigree
Austenite grain boundaries
Interfacial morphology
Free oxygen
Stainless steel
Mould flux
Reheating
Hydraulic descaling
Internal oxidation
UCTD
url http://hdl.handle.net/2263/29840
http://upetd.up.ac.za/thesis/available/etd-11262009-192807/