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Electrical characterization of process and irradiation induced defects in GaAs

Dissertation (MSc)--University of Pretoria, 2016.

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Other Authors: Diale, M. (Mmantsae Moche)
Format: Thesis
Language:English
Published: University of Pretoria 2016
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author2 Diale, M. (Mmantsae Moche)
author_browse Diale, M. (Mmantsae Moche)
author_facet Diale, M. (Mmantsae Moche)
collection Thesis
dc_rights_str_mv © 2016, University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria.
description Dissertation (MSc)--University of Pretoria, 2016.
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institution University of Pretoria (South Africa)
language English
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provenance_str_mv Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository
publishDate 2016
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spelling oai:repository.up.ac.za:2263/53562 Electrical characterization of process and irradiation induced defects in GaAs Diale, M. (Mmantsae Moche) u13259394@tuks.co.za Auret, F.D. (Francois Danie) Tunhuma, Shandirai Malven UCTD Dissertation (MSc)--University of Pretoria, 2016. Gallium arsenide (GaAs) technology leads the implementation of high frequency devices with superior performance. A vast number of optoelectronic applications are based on the material owing to its direct and wide bandgap. Over the years the number of these applications continues to grow but they remain highly cost-ineffective partly due to the growth techniques and the presence of defects in GaAs. These areas have been researched on intensively over the past four decades with much controversy, particularly on the subject of the EL2 defect. This defect plays an important role in the design and operation of GaAs based devices. It is therefore important to understand its electronic properties and influence on device operation. Schottky barrier diodes (SBDs) were fabricated on n-type GaAs. The quality of the contacts was evaluated using current-voltage (I-V) and capacitance-voltage (C-V) measurements before and after exposing them to different processing techniques and radiation types. Deep-level transient spectroscopy (DLTS) and Laplace deeplevel transient spectroscopy (L-DLTS) were used to characterize the electrically active defects in the material. Defects with almost similar emission rates which were not observed in the past were identified using L-DLTS due to its high resolution. I-V and C-V measurements on as-deposited Au/n-GaAs SBDs in the 80 ?? 480 K range showed that the EL2 defect has a profound effect on the diode characteristics. The influence of the defect caused the temperature dependent behavior of the C-V barrier height to be split into two temperature intervals, each with a unique temperature coefficient. Exposure of the devices to temperatures above 300 K resulted in the deterioration of their I-V characteristics. Permanent physical modification of the SBDs was observed at 400 K and above. Inductively coupled plasma (ICP) etching, Electron beam deposition (EBD) and electron beam exposure (EBE) were observed to impact significantly on diode I-V and C-V characteristics. ICP etching resulted in devices with a lower reverse leakage current and high barrier height whereas EBD fabricated devices exhibited the poorest characteristics. DLTS results revealed that processing introduced electrically active defects in the bandgap. EBE induced defects had different electronic properties to all the processing and radiation induced defects observed in previous studies. I-V and C-V characteristics of SBDs exposed to alpha and beta-particle irradiation were identical to as-deposited samples. This demonstrated the radiation hardness of GaAs. DLTS spectra of alpha-particle irradiated SBDs displayed the defect peaks sitting on a skewed baseline which hampered accurate L-DLTS measurements. In addition to the prominent irradiation induced defects, high energy electron-irradiation was observed to induce defects with electronic properties similar to those of the EL2. Physics MSc Unrestricted 2016-07-01T10:33:55Z 2016-07-01T10:33:55Z 2016-04-05 2016 Dissertation Tunhuma, SM 2016, Electrical characterization of process and irradiation induced defects in GaAs, MSc Dissertation, University of Pretoria, Pretoria, viewed yymmdd <http://hdl.handle.net/2263/53562> A2016 http://hdl.handle.net/2263/53562 en © 2016, University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria
spellingShingle UCTD
Electrical characterization of process and irradiation induced defects in GaAs
title Electrical characterization of process and irradiation induced defects in GaAs
title_full Electrical characterization of process and irradiation induced defects in GaAs
title_fullStr Electrical characterization of process and irradiation induced defects in GaAs
title_full_unstemmed Electrical characterization of process and irradiation induced defects in GaAs
title_short Electrical characterization of process and irradiation induced defects in GaAs
title_sort electrical characterization of process and irradiation induced defects in gaas
topic UCTD
url http://hdl.handle.net/2263/53562