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Prioritisation of emerging chemical pollutants in South African water resources

Dissertation (MSc)--University of Pretoria, 2016.

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Other Authors: Forbes, Patricia B.C.
Format: Thesis
Language:English
Published: University of Pretoria 2016
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access_status_str Open Access
author2 Forbes, Patricia B.C.
author_browse Forbes, Patricia B.C.
author_facet Forbes, Patricia B.C.
collection Thesis
dc_rights_str_mv © 2016 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria.
description Dissertation (MSc)--University of Pretoria, 2016.
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institution University of Pretoria (South Africa)
language English
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license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository
publishDate 2016
publishDateRange 2016
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publisher University of Pretoria
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spelling oai:repository.up.ac.za:2263/57282 Prioritisation of emerging chemical pollutants in South African water resources Forbes, Patricia B.C. u10197762@tuks.co.za Petersen, Fritz UCTD Dissertation (MSc)--University of Pretoria, 2016. Emerging chemical pollutants (ECPs) are defined as new chemicals which do not have a regulatory status, but which may have an adverse effect on human health and the environment. Sources and environmental pathways of these ECPs have been increasingly associated with waste and wastewaters arising from industrial, agricultural and municipal activities. The ECPs of current concern include a wide range of compounds including polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), brominated flame retardants (BFRs), antivirals, antiretrovirals, pesticides, phthalates, disinfectants, psycho-stimulants, diuretics, cosmetics, contrast media, neuroactive compounds, blood lipid lowering agents, beta-blockers, antibiotics and, analgesics and anti-inflammatory drugs. There is currently a lack of information regarding the nature, concentration, variability, transport and fate of these compounds in water, which is of global concern. A recent South African survey on emerging contaminants in drinking water in South Africa detected a total of 34 pharmaceuticals or pesticides, which indicates the need for more research in this area. In this study a prioritisation methodology for emerging chemical pollutants in water was developed and used. A group of 168 ECPs were prioritised based on various factors including toxicity (acute toxicity in rats), environmental persistence (half-life in water), relevant physicochemical data (partition coefficient) and global prevalence. The ECPs were then ranked by assigning weightings to these factors. The ranks each substance obtained were then summed across all the factors in order to obtain a final weighting for each substance. Each substance was then ranked in accordance with its final summed total which resulted in a ranked list of priority ECPs. After the prioritisation process, it became apparent that pesticides were a class of compounds that warranted further studies as they accounted for many of the highest ranked ECPs. The full list of ranked ECPs generated can prove to be an invaluable starting point for further research into ECPs in South African water bodies and to compare various ECPs with each other in term of their persistence, bioaccumulation and toxicity and thus the hazard they pose to the environment. Additionally, relevant surface water sampling sites in the Gauteng Province of South Africa were identified utilising a geographic information system (GIS) to generate maps. The sites were identified by identifying potential sources of ECPs, including hospitals and clinics, sewage treatment plants, and areas with high population densities or areas that were vulnerable from an environmental point of view. Buffers were drawn around these areas to identify the water sources which have the highest probability of containing the relevant ECPs. The wards that are located along the identified at-risk river areas were also identified in an attempt to aid decision and policy makers within both the private sector and government in making informed decisions regarding ECPs. tm2016 Zoology and Entomology MSc Unrestricted 2016-10-14T07:33:03Z 2016-10-14T07:33:03Z 2016-09-01 2016 Dissertation Petersen, F 2016, Prioritisation of emerging chemical pollutants in South African water resources, MSc Dissertation, University of Pretoria, Pretoria, viewed yymmdd <http://hdl.handle.net/2263/57282> S2016 http://hdl.handle.net/2263/57282 en © 2016 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria
spellingShingle UCTD
Prioritisation of emerging chemical pollutants in South African water resources
title Prioritisation of emerging chemical pollutants in South African water resources
title_full Prioritisation of emerging chemical pollutants in South African water resources
title_fullStr Prioritisation of emerging chemical pollutants in South African water resources
title_full_unstemmed Prioritisation of emerging chemical pollutants in South African water resources
title_short Prioritisation of emerging chemical pollutants in South African water resources
title_sort prioritisation of emerging chemical pollutants in south african water resources
topic UCTD
url http://hdl.handle.net/2263/57282