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Local development and calibration of a passive sampler for monitoring of particulate matter

Dissertation (MEng)--University of Pretoria, 2019.

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Other Authors: Kornelius, Gerrit
Format: Thesis
Language:English
Published: University of Pretoria 2020
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access_status_str Open Access
author2 Kornelius, Gerrit
author_browse Kornelius, Gerrit
author_facet Kornelius, Gerrit
collection Thesis
dc_rights_str_mv © 2019 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria.
description Dissertation (MEng)--University of Pretoria, 2019.
format Thesis
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institution University of Pretoria (South Africa)
language English
last_indexed 2026-06-10T12:37:00.236Z
license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository
publishDate 2020
publishDateRange 2020
publishDateSort 2020
publisher University of Pretoria
publisherStr University of Pretoria
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source_str UPSpace — University of Pretoria Institutional Repository
spelling oai:repository.up.ac.za:2263/73458 Local development and calibration of a passive sampler for monitoring of particulate matter Kornelius, Gerrit u16255781@tuks.co.za Mukota, Tinashe Air Quality Monitoring UCTD Engineering, built environment and information technology theses SDG-03 Engineering, built environment and information technology theses SDG-09 Engineering, built environment and information technology theses SDG-11 Engineering, built environment and information technology theses SDG-13 Dissertation (MEng)--University of Pretoria, 2019. The measurement of ambient particulate concentration (PM10 and PM2.5) using active monitors requires expensive or labour-intensive apparatus or both. Although PM is a priority pollutant, this has precluded widespread or intensive ambient particulate monitoring networks to be set up in South Africa, except in some priority areas. In this study, locally manufactured passive PM monitoring devices (samplers), based on a design initially published by researchers at the University of North Carolina (UNC), were calibrated for the measurement of PM10-2.5. Duplicate samplers of each type (local and UNC) were co-located at eight reference stations equipped with TEOM (Tapered element oscillating microbalance) or BAM (Beta radiation attenuation monitor) particulate monitors in three networks. Imaging of the substrate was carried out using an optical microscope to limit the cost of analysis. The images (10 to 49 per sample) were analysed using both proprietary (Zeiss AxioVision®) and open-source (ImageJ) software at 100X and 200X magnification. Considerable variation exists between the four co-located local and UNC samplers at all stations, although the latter show lesser discrepancies when analysed using the AxioVision software. Greater agreement of the local samplers and the continuous monitors is noted at a 200X and 100X magnification using the AxioVision software with R2 = 0.81 and R2 = 0.79 respectively. The precision of PM10-2.5 measured with the passive samplers was highly variable with calculated CVs ranging from 10.4% to 73.3%. 82% of the CVs were less than 40%. The average CV for all samplers was 34.6%. Passive samplers analysed using the AxioVision software recorded smaller average discrepancies of 45.3% at 100X and 37.3% at 200X magnification. Samplers analysed using ImageJ at 100X magnification exhibited the highest percentage difference from the reference values (81.2%). Using a two factor ANOVA we can show that (at 95% confidence) the analysis software and the imaging magnification have the most significant effect on the calculated sampler concentration results. A disadvantage of passive samplers is large number of days (2-7) required to produce statistically significant values hence disqualifying it for use as a reference method. The device is, therefore, more suitable for screening-level, high spatial density sampling, but some non-regulatory applications are pointed out. mi2026 Chemical Engineering MEng (Environmental Engineering) Unrestricted SDG-03: Good health and well-being SDG-09: Industry, innovation and infrastructure SDG-11: Sustainable cities and communities SDG-13: Climate action 2020-02-20T13:31:55Z 2020-02-20T13:31:55Z 2020-04-14 2019-10 Dissertation Mukota, T 2019, Local development and calibration of a passive sampler for monitoring of particulate matter, MEng (Environmental Engineering) Dissertation, University of Pretoria, Pretoria, viewed yymmdd <http://hdl.handle.net/2263/73458> A2020 http://hdl.handle.net/2263/73458 en © 2019 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria
spellingShingle Air Quality Monitoring
UCTD
Engineering, built environment and information technology theses SDG-03
Engineering, built environment and information technology theses SDG-09
Engineering, built environment and information technology theses SDG-11
Engineering, built environment and information technology theses SDG-13
Local development and calibration of a passive sampler for monitoring of particulate matter
title Local development and calibration of a passive sampler for monitoring of particulate matter
title_full Local development and calibration of a passive sampler for monitoring of particulate matter
title_fullStr Local development and calibration of a passive sampler for monitoring of particulate matter
title_full_unstemmed Local development and calibration of a passive sampler for monitoring of particulate matter
title_short Local development and calibration of a passive sampler for monitoring of particulate matter
title_sort local development and calibration of a passive sampler for monitoring of particulate matter
topic Air Quality Monitoring
UCTD
Engineering, built environment and information technology theses SDG-03
Engineering, built environment and information technology theses SDG-09
Engineering, built environment and information technology theses SDG-11
Engineering, built environment and information technology theses SDG-13
url http://hdl.handle.net/2263/73458