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Synthesis and characterization of caesium lead tri-iodide for solar cells
Dissertation (MSc (Physics))--Univeristy of Pretoria 2022.
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| Format: | Thesis |
| Language: | English |
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University of Pretoria
2022
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| _version_ | 1867613665412251648 |
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| access_status_str | Open Access |
| author2 | Diale, M. (Mmantsae Moche) |
| author_browse | Diale, M. (Mmantsae Moche) |
| author_facet | Diale, M. (Mmantsae Moche) |
| collection | Thesis |
| dc_rights_str_mv | © 2022 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. |
| description | Dissertation (MSc (Physics))--Univeristy of Pretoria 2022. |
| format | Thesis |
| id | oai:repository.up.ac.za:2263/86595 |
| institution | University of Pretoria (South Africa) |
| language | English |
| last_indexed | 2026-06-10T12:39:45.647Z |
| license_str | Other — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository |
| publishDate | 2022 |
| publishDateRange | 2022 |
| publishDateSort | 2022 |
| publisher | University of Pretoria |
| publisherStr | University of Pretoria |
| record_format | dspace |
| source_str | UPSpace — University of Pretoria Institutional Repository |
| spelling | oai:repository.up.ac.za:2263/86595 Synthesis and characterization of caesium lead tri-iodide for solar cells Diale, M. (Mmantsae Moche) drbheki636@gmail.com Nombona, Nolwazi Sibiya, Sizwe Bhekithemba Caesium Iodide Sequential physical vapour deposition Solar cells Caesium lead tri-iodide Thin film UCTD Dissertation (MSc (Physics))--Univeristy of Pretoria 2022. In this study, we report on the synthesis and characterization of titanium dioxide thin film prepared via the spray pyrolysis technique. X-ray diffractograms confirmed a tetragonal crystal structure with an average crystallite size of 24.44 nm and a micro-strain of 9.75x10-4. Field-emission scanning electron micrographs show pin-hole-free and densely packed grains with an average size ranging from 25 to 29 nm. UV-Vis spectra revealed an absorption onset of 300 nm for the film. The estimated film bandgap was 3.9 eV. The sequential physical vapour deposition technique was used to grow quality thick films of metal halide perovskites in a safe, scalable, and reproducible manner. Growth of high-quality poly-crystalline yellow phase caesium lead tri-iodide (CsPbI3) was refined by varying the CsI thickness from 200 nm to 500 nm. Crystallographic parameters and phase transitions from as-deposited orthorhombic γ-CsPbI3 to tetragonal β-CsPbI3 on annealing at 100 ℃, were determined using X-ray diffraction patterns. Computed lattice constants were a= 4.88 Å, b= 9.96 Å, and c= 16.52 Å, with an average crystallite size increasing from 169.46 nm to 243 nm, and the micro-strains decreased with an increase of CsI thickness. The field-emission scanning electron micrographs showed a uniform surface covered with polycrystalline grains. The Average grain size increased from 168 to 235 nm as the caesium iodide (CsI) thickness increased, resulting in large pin-hole-free and tightly packed grains. A 2.24 to 2.38 eV increase in the bandgap was observed when CsI thickness was increased. Herein, we demonstrated optimized structural, morphological, and optical properties of CsPbI3 for use in solar cells, grown via sequential physical vapour deposition technique for stable and completely inorganic perovskites. Finally, the electrical properties of fabricated FTO/TiO2/CsPbI3/Au devices were characterized using the current-density (I-V) measurement technique. Although the CsI thickness varied, it had no effect on the cell's performance because the devices showed consistent power conversion efficiency of about 4%. Moreover, the open circuit voltage shows a decreasing trend when CsI thickness decreases. National Research Foundation (NRF) SARCHI - Clean and green energy University of Pretoria (UP) Physics MSc (Physics) Unrestricted 2022-07-29T10:12:26Z 2022-07-29T10:12:26Z 2022-09-08 2022-03 Dissertation * S2022 https://repository.up.ac.za/handle/2263/86595 DOI: 10.25403/UPresearchdata.20372025 1025403/UPresearchdata.20372025 en © 2022 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria |
| spellingShingle | Caesium Iodide Sequential physical vapour deposition Solar cells Caesium lead tri-iodide Thin film UCTD Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title | Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title_full | Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title_fullStr | Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title_full_unstemmed | Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title_short | Synthesis and characterization of caesium lead tri-iodide for solar cells |
| title_sort | synthesis and characterization of caesium lead tri iodide for solar cells |
| topic | Caesium Iodide Sequential physical vapour deposition Solar cells Caesium lead tri-iodide Thin film UCTD |
| url | https://repository.up.ac.za/handle/2263/86595 |