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Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications
Thesis (PhD (Physics))--University of Pretoria, 2022.
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| Format: | Thesis |
| Language: | English |
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University of Pretoria
2022
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| _version_ | 1867613518219444224 |
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| access_status_str | Open Access |
| author2 | Manyala, Ncholu I. |
| author_browse | Manyala, Ncholu I. |
| author_facet | Manyala, Ncholu I. |
| collection | Thesis |
| dc_rights_str_mv | © 2022 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. |
| description | Thesis (PhD (Physics))--University of Pretoria, 2022. |
| format | Thesis |
| id | oai:repository.up.ac.za:2263/88798 |
| institution | University of Pretoria (South Africa) |
| language | English |
| last_indexed | 2026-06-10T12:37:25.198Z |
| license_str | Other — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository |
| publishDate | 2022 |
| publishDateRange | 2022 |
| publishDateSort | 2022 |
| publisher | University of Pretoria |
| publisherStr | University of Pretoria |
| record_format | dspace |
| source_str | UPSpace — University of Pretoria Institutional Repository |
| spelling | oai:repository.up.ac.za:2263/88798 Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications Manyala, Ncholu I. rutavigift@yahoo.com Rutavi, Gift UCTD Electrodeposition Layered double hydroxides Renewable energy Spinels Thesis (PhD (Physics))--University of Pretoria, 2022. In this thesis, “Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications”, an efficient binder-free electrodeposition process was used to prepare cobalt nickel layered double hydroxide and its composites. Cobalt nickel layered double hydroxide (CN-LDH) benefits from a unique 2D layered structure with large interlayer spacing for ion transport. However, it suffers from restacking of layers leading to low electrical conductivity. Sulphur reduced graphene oxide increases mechanical strength, electrical conductivity, and wettability, while Hausmannite, manganese cobaltite and chromite improves the redox active capability and ion diffusion to improve the electrochemical performance of CN-LDH. The asymmetric supercapacitors fabricated using CN-LDH composites as positive electrodes and activated carbon as negative electrodes, exhibited excellent specific energy and power ranging from 55.8 to 80.2 W h kg -1 and 515 to 1117.7 W kg -1 , respectively, in 2 M KOH electrolyte within a cell voltage of 1.65 V. National Research Foundation Physics PhD (Physics) Unrestricted 2022-12-14T11:39:56Z 2022-12-14T11:39:56Z 2023-04 2022 Thesis * A2023 https://repository.up.ac.za/handle/2263/88798 DOI: https://doi.org/10.25403/UPresearchdata.21717062.v1 https://doi.org/10.25403/UPresearchdata.21717062.v1 en © 2022 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria |
| spellingShingle | UCTD Electrodeposition Layered double hydroxides Renewable energy Spinels Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title | Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title_full | Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title_fullStr | Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title_full_unstemmed | Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title_short | Characterization and performance evaluation of electrodeposition synthesized cobalt-nickel layered double hydroxide and composites for high-efficiency hybrid capacitor applications |
| title_sort | characterization and performance evaluation of electrodeposition synthesized cobalt nickel layered double hydroxide and composites for high efficiency hybrid capacitor applications |
| topic | UCTD Electrodeposition Layered double hydroxides Renewable energy Spinels |
| url | https://repository.up.ac.za/handle/2263/88798 https://doi.org/10.25403/UPresearchdata.21717062.v1 |