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Thesis (PhD)--University of Pretoria, 1989.
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| Format: | Thesis |
| Language: | English |
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University of Pretoria
2024
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| _version_ | 1867613690561298432 |
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| access_status_str | Open Access |
| author2 | Heyns, A.M. |
| author_browse | Heyns, A.M. |
| author_facet | Heyns, A.M. |
| collection | Thesis |
| dc_rights_str_mv | © 2024 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. |
| description | Thesis (PhD)--University of Pretoria, 1989. |
| format | Thesis |
| id | oai:repository.up.ac.za:2263/99511 |
| institution | University of Pretoria (South Africa) |
| language | English |
| last_indexed | 2026-06-10T12:40:09.614Z |
| license_str | Other — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UPSpace — University of Pretoria Institutional Repository |
| publishDate | 2024 |
| publishDateRange | 2024 |
| publishDateSort | 2024 |
| publisher | University of Pretoria |
| publisherStr | University of Pretoria |
| record_format | dspace |
| source_str | UPSpace — University of Pretoria Institutional Repository |
| spelling | oai:repository.up.ac.za:2263/99511 Applications of Raman spectroscopy to solid state chemistry Heyns, A.M. Venter, Myrl Wendy Applications Raman spectroscopy Solid state chemistry UCTD Thesis (PhD)--University of Pretoria, 1989. Two investigations of solid state chemistry problems, using various aspects of Raman spectroscopy, are described. The first includes high pressure studies of pyridine and ZnCl2py2. Both of these studies gave phases which have not previously been described. Single crystal polarization studies on CdC12py2 and CuC12py2 gave unambiguous assignments of the lattice vibrations in the polymeric octahedral complexes, which were subsequently used to show that the higher pressure phase of ZnC12py2 belongs to the polymeric octahedral class of structures. The second investigation showed that the decomposition of ammonium metavanadate under ambient pressures to vanadium pentoxide proceeds via the intermediate ammonium hexavanadate. An important contribution was also made in terms of the elucidation of the vibrational spectra of these compounds using techniques such as deuteration, high pressures and temperatures. Chemistry PhD 2024-11-27T09:16:03Z 2024-11-27T09:16:03Z 21/12/14 1989 Thesis http://hdl.handle.net/2263/99511 en © 2024 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. application/pdf University of Pretoria |
| spellingShingle | Applications Raman spectroscopy Solid state chemistry UCTD Applications of Raman spectroscopy to solid state chemistry |
| title | Applications of Raman spectroscopy to solid state chemistry |
| title_full | Applications of Raman spectroscopy to solid state chemistry |
| title_fullStr | Applications of Raman spectroscopy to solid state chemistry |
| title_full_unstemmed | Applications of Raman spectroscopy to solid state chemistry |
| title_short | Applications of Raman spectroscopy to solid state chemistry |
| title_sort | applications of raman spectroscopy to solid state chemistry |
| topic | Applications Raman spectroscopy Solid state chemistry UCTD |
| url | http://hdl.handle.net/2263/99511 |