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Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide

Thesis (MEng)--Stellenbosch University, 2020.

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Main Author: Vlok, Thomas Leslie Stewart
Other Authors: Croukamp, Leon
Format: Thesis
Language:English
Published: Stellenbosch : Stellenbosch University 2020
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access_status_str Open Access
author Vlok, Thomas Leslie Stewart
author2 Croukamp, Leon
author_browse Croukamp, Leon
Vlok, Thomas Leslie Stewart
author_facet Croukamp, Leon
Vlok, Thomas Leslie Stewart
author_sort Vlok, Thomas Leslie Stewart
collection Thesis
dc_rights_str_mv Stellenbosch University
description Thesis (MEng)--Stellenbosch University, 2020.
format Thesis
id oai:scholar.sun.ac.za:10019.1/107814
institution Stellenbosch University (South Africa)
language English
last_indexed 2026-06-10T12:46:25.318Z
license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from SUNScholar — Stellenbosch University Repository
publishDate 2020
publishDateRange 2020
publishDateSort 2020
publisher Stellenbosch : Stellenbosch University
publisherStr Stellenbosch : Stellenbosch University
record_format dspace
source_str SUNScholar — Stellenbosch University Repository
spelling oai:scholar.sun.ac.za:10019.1/107814 Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide Vlok, Thomas Leslie Stewart Croukamp, Leon Stellenbosch University. Faculty of Engineering. Dept. of Civil Engineering. Clay soil -- Permeability Geotechnical engineering Soil mineralogy Soil structure UCTD Swelling soils Chlorine dioxide Drainage Thesis (MEng)--Stellenbosch University, 2020. ENGLISH ABSTRACT: Clay particles have small particle sizes. With the addition of water, the change in volume is greater in clay soils than coarse grained soils. When clay soils are mixed with a coarse-grained soil, the shrink and swell potential of the mixed soil will decrease. Chlorine dioxide is commonly used as a disinfectant or to control algae growth in sedimentation and flocculation basins. This chemical is used to kill bacteria in soil as well. Another use of chlorine dioxide is to increase the permeability of sandstone formations through the reaction of clays in these formations. The aim of this study is to determine if the increase in permeability as observed in the field can be replicated in the laboratory, by using the same concentration of chlorine dioxide that is used in agriculture to kill bacteria in the soil. The soil was treated with diluted chlorine dioxide to investigate the effect on the soil mineralogy and soil structure. Two different soils were used for these experiments. The first experiment was conducted with a clay soil. The second was a mixture of clay soil at the bottom with a coarse-grained soil on top to simulate different scenarios. Chlorine dioxide was mixed with water at different concentrations and introduced into the soil at a constant rate with a drip system. The chlorine dioxide is applied once then every third day for two weeks and then four litres of clean water was introduced into the soil with the same drip system. The soil was then dried and prepared for tests. X-Ray Fluorescence and X-Ray Diffraction was done on the soil to determine the mineralogy.A sieve analysis gave the particle size distribution for each sample. CT scan and scanning electron microscope tests were done to compare the soil structure before and after the experiment. A falling head permeability tests was also done on an untreated and treated sample to compare drainage of the soil. This study showed the mineralogy of the soil is not affected by chlorine dioxide. The CT scan showed the voids increase after the chlorine dioxide treatment. The scanning electron microscope showed the particles coalesced into flocculated layers, but the scans does not confirm the increase in void ratio from the CT scan. Particle size distribution does not show significant changes after the chlorine dioxide treatment. Chlorine dioxide treatment improved the drainage of the clay soil. Therefore, this treatment can be used to improve the permeability of clay soil. AFRIKAANSE OPSOMMING: Geen opsomming Masters 2020-02-07T14:23:45Z 2020-04-28T12:04:43Z 2020-02-07T14:23:45Z 2020-04-28T12:04:43Z 2020-03 Thesis http://hdl.handle.net/10019.1/107814 en Stellenbosch University x, 70 leaves : illustrations (some color) application/pdf Stellenbosch : Stellenbosch University
spellingShingle Clay soil -- Permeability
Geotechnical engineering
Soil mineralogy
Soil structure
UCTD
Swelling soils
Chlorine dioxide
Drainage
Vlok, Thomas Leslie Stewart
Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title_full Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title_fullStr Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title_full_unstemmed Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title_short Changing the permeability, mineral and soil structure of clay soil with chlorine dioxide
title_sort changing the permeability mineral and soil structure of clay soil with chlorine dioxide
topic Clay soil -- Permeability
Geotechnical engineering
Soil mineralogy
Soil structure
UCTD
Swelling soils
Chlorine dioxide
Drainage
url http://hdl.handle.net/10019.1/107814
work_keys_str_mv AT vlokthomaslesliestewart changingthepermeabilitymineralandsoilstructureofclaysoilwithchlorinedioxide