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Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics
Thesis (MSc (Chemistry and Polymer Science))--Stellenbosch University, 2008.
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| Format: | Thesis |
| Language: | en_ZA |
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Stellenbosch : Stellenbosch University
2008
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| _version_ | 1867613945787842560 |
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| access_status_str | Open Access |
| author | De Jongh, Leigh-Anne |
| author2 | Cronje, S. |
| author_browse | Cronje, S. De Jongh, Leigh-Anne |
| author_facet | Cronje, S. De Jongh, Leigh-Anne |
| author_sort | De Jongh, Leigh-Anne |
| collection | Thesis |
| dc_rights_str_mv | Stellenbosch University |
| description | Thesis (MSc (Chemistry and Polymer Science))--Stellenbosch University, 2008. |
| format | Thesis |
| id | oai:scholar.sun.ac.za:10019.1/2001 |
| institution | Stellenbosch University (South Africa) |
| language | en_ZA |
| last_indexed | 2026-06-10T12:44:12.049Z |
| license_str | Other — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from SUNScholar — Stellenbosch University Repository |
| publishDate | 2008 |
| publishDateRange | 2008 |
| publishDateSort | 2008 |
| publisher | Stellenbosch : Stellenbosch University |
| publisherStr | Stellenbosch : Stellenbosch University |
| record_format | dspace |
| source_str | SUNScholar — Stellenbosch University Repository |
| spelling | oai:scholar.sun.ac.za:10019.1/2001 Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics De Jongh, Leigh-Anne Cronje, S. Raubenheimer, H. G. Stellenbosch University. Faculty of Science. Dept. of Chemistry and Polymer Science. Imine coordination Gold complexes Chromium Tungsten Dissertations -- Chemistry Theses -- Chemistry Coordination compounds Ligands Chemistry and Polymer Science Thesis (MSc (Chemistry and Polymer Science))--Stellenbosch University, 2008. In this study the coordination of ligands with several coordination sites, 2-aminoazoles (2- amino-4-methylthiazole), 2-aminobenzothiazole, 2-aminobenzoimidazole and 2- aminothiazoline and a biguanidine (N-(2-methylphenyl)imidodicarbonimidic diamide) to soft metal centres [gold(I) (group 11), chromium(0) (group 6) and tungsten (0) (group 6)] was investigated. The aminoazoles have three coordination sites, an exocyclic amine nitrogen, an endocyclic imine nitrogen and an endocyclic thioether sulphur. The biguanidine ligand has three sites for deprotonation, one central amine and two imine nitrogens, and at least five sites available for nitrogen coordination. 2008-09-16T08:24:11Z 2010-06-01T08:38:32Z 2008-09-16T08:24:11Z 2010-06-01T08:38:32Z 2008-12 Thesis http://hdl.handle.net/10019.1/2001 en_ZA Stellenbosch University application/pdf Stellenbosch : Stellenbosch University |
| spellingShingle | Imine coordination Gold complexes Chromium Tungsten Dissertations -- Chemistry Theses -- Chemistry Coordination compounds Ligands Chemistry and Polymer Science De Jongh, Leigh-Anne Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title | Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title_full | Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title_fullStr | Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title_full_unstemmed | Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title_short | Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics |
| title_sort | imine donor complexes with group 6 and group 11 transition metals coordination and dynamics |
| topic | Imine coordination Gold complexes Chromium Tungsten Dissertations -- Chemistry Theses -- Chemistry Coordination compounds Ligands Chemistry and Polymer Science |
| url | http://hdl.handle.net/10019.1/2001 |
| work_keys_str_mv | AT dejonghleighanne iminedonorcomplexeswithgroup6andgroup11transitionmetalscoordinationanddynamics |