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Translocation of a polymer chain under geometric confinement

Thesis (MSc)--Stellenbosch University, 2014.

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Main Author: Gumede, Sthembiso R.
Other Authors: Muller-Nedebock, Kristian K.
Format: Thesis
Language:en_ZA
Published: Stellenbosch : Stellenbosch University 2014
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access_status_str Open Access
author Gumede, Sthembiso R.
author2 Muller-Nedebock, Kristian K.
author_browse Gumede, Sthembiso R.
Muller-Nedebock, Kristian K.
author_facet Muller-Nedebock, Kristian K.
Gumede, Sthembiso R.
author_sort Gumede, Sthembiso R.
collection Thesis
dc_rights_str_mv Stellenbosch University
description Thesis (MSc)--Stellenbosch University, 2014.
format Thesis
id oai:scholar.sun.ac.za:10019.1/86630
institution Stellenbosch University (South Africa)
language en_ZA
last_indexed 2026-06-10T12:41:21.859Z
license_str Other — see source repository
provenance_str_mv Harvested via OAI-PMH from SUNScholar — Stellenbosch University Repository
publishDate 2014
publishDateRange 2014
publishDateSort 2014
publisher Stellenbosch : Stellenbosch University
publisherStr Stellenbosch : Stellenbosch University
record_format dspace
source_str SUNScholar — Stellenbosch University Repository
spelling oai:scholar.sun.ac.za:10019.1/86630 Translocation of a polymer chain under geometric confinement Gumede, Sthembiso R. Muller-Nedebock, Kristian K. Muller-Nedebock, Kristian K. Polymers Polymers -- Physiological transport Theoretical physics Translocation (Genetics) UCTD Dissertations -- Physics Theses -- Physics Thesis (MSc)--Stellenbosch University, 2014. ENGLISH ABSTRACT: The advent of the synthesis or manufacturing of controlled structures on submicron scales as well as experimental developments enabling the investigation of physics in speci c biological systems at extremely small length scales underlines the need for dealing with the statistical physics of small systems which are geometrically con ned. A typical example of a system for which physical questions can be answered by means of theoretical modelling is the virus, where polymer genetic material is encapsulated in a protein shell. In this project the role of con nement on polymer chains will be investigated. We investigate how the translocation of polymer from one region to another through a small opening depends on various electrolytic, polymer concentration and wall interaction conditions. This is an extension of the simple, purely entropic, picture in that the interaction terms enter the picture. We employ a variational scheme in deriving our results. AFRIKAANSE OPSOMMING: Sowel die moontlikheid van beheerbare sintese of vervaardiging van strukture op sub-mikrometer lengteskale asook die koms van eksperimentele metodes vir die ondersoek van biologiese stelsels op baie klein lengteskale onderstreep hoe nodig dit is om die statiestiese sika van klein stelsels met geometriese beperkings te verstaan. 'n Tipiese voorbeeld waar teoretiese metodes vir siese vrae aangewend word is 'n virus, waar die polimeriese genetiese materiaal in 'n proteïen skil beweeg. In die huidge projek word die rol van 'n spesi eke geometriese beperking op polimeerkettings ondersoek. Ons ondersoek hoe die oorplasing van 'n polimeer deur 'n klein opening van een gebied na die ander deur verskillende elektrolietiese, polimeer-konsentrasie en wandinteraksie eienskappe afhang. Dit is 'n uitbreiding van die eenvoudige, volledig entropiese beeld vir oorplasing deurdat wisselwerkings ingesluit word. 'n Variasiebeginsel word aangewend om die resultate af te lei. 2014-04-16T17:30:41Z 2014-04-16T17:30:41Z 2014-04 Thesis http://hdl.handle.net/10019.1/86630 en_ZA Stellenbosch University vi, 75 p. application/pdf Stellenbosch : Stellenbosch University
spellingShingle Polymers
Polymers -- Physiological transport
Theoretical physics
Translocation (Genetics)
UCTD
Dissertations -- Physics
Theses -- Physics
Gumede, Sthembiso R.
Translocation of a polymer chain under geometric confinement
title Translocation of a polymer chain under geometric confinement
title_full Translocation of a polymer chain under geometric confinement
title_fullStr Translocation of a polymer chain under geometric confinement
title_full_unstemmed Translocation of a polymer chain under geometric confinement
title_short Translocation of a polymer chain under geometric confinement
title_sort translocation of a polymer chain under geometric confinement
topic Polymers
Polymers -- Physiological transport
Theoretical physics
Translocation (Genetics)
UCTD
Dissertations -- Physics
Theses -- Physics
url http://hdl.handle.net/10019.1/86630
work_keys_str_mv AT gumedesthembisor translocationofapolymerchainundergeometricconfinement