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Solid-state dynamics of porous materials
Thesis (PhD)--Stellenbosch University, 2013.
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| Other Authors: | |
| Format: | Thesis |
| Language: | en_ZA |
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Stellenbosch : Stellenbosch University
2013
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| _version_ | 1867614015640829952 |
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| access_status_str | Open Access |
| author | Grobler, Ilne |
| author2 | Barbour, Leonard J. |
| author_browse | Barbour, Leonard J. Grobler, Ilne |
| author_facet | Barbour, Leonard J. Grobler, Ilne |
| author_sort | Grobler, Ilne |
| collection | Thesis |
| dc_rights_str_mv | Stellenbosch University |
| description | Thesis (PhD)--Stellenbosch University, 2013. |
| format | Thesis |
| id | oai:scholar.sun.ac.za:10019.1/95478 |
| institution | Stellenbosch University (South Africa) |
| language | en_ZA |
| last_indexed | 2026-06-10T12:45:19.124Z |
| license_str | Other — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from SUNScholar — Stellenbosch University Repository |
| publishDate | 2013 |
| publishDateRange | 2013 |
| publishDateSort | 2013 |
| publisher | Stellenbosch : Stellenbosch University |
| publisherStr | Stellenbosch : Stellenbosch University |
| record_format | dspace |
| source_str | SUNScholar — Stellenbosch University Repository |
| spelling | oai:scholar.sun.ac.za:10019.1/95478 Solid-state dynamics of porous materials Grobler, Ilne Barbour, Leonard J. Esterhuysen, Catharine Stellenbosch University. Faculty of Science. Dept. of Chemistry and Polymer Science. Porosity Supramolecular chemistry Crystal engineering Inclusion compounds Absorption Porous materials Guest-exchange process Dissertations -- Chemistry and Polymer Science Thesis (PhD)--Stellenbosch University, 2013. ENGLISH ABSTRACT: A number of porous metal-organic and organic crystalline materials were prepared with a view to study the solid-state dynamics involved in sorption and guest-exchange processes. The main goal was to gain an understanding of the mechanisms involved in structural changes induced by external stimuli. To this end, single-crystal X-ray diffraction (SCD) experiments were carried out under variable temperature and pressure conditions, supplemented by thermal analysis and sorption experiments. AFRIKAANSE OPSOMMING: 'n Aantal poreuse metaal-organiese en organiese kristallyne materiale is berei met die doel om die vaste-toestand dinamika wat betrokke is in sorpsie en gas-uitruil (E. guest-exchange) prosesse te ondersoek. Die hoofdoel is om 'n begrip van die meganismes wat betrokke is in die strukturele veranderinge veroorsaak deur eksterne stimuli, te verkry. Dus is enkel-kristal X-straal-diffraksie eksperimente uitgevoer onder verskeie temperatuur- en drukkondisies. Die X-straal diffraksie eksperimente is aangevul deur termo-analise (E. thermal analysis) en sorpsie eksperimente. Doctoral 2013-11-19T10:34:39Z 2014-01-21T09:25:33Z 2014-07-10T09:35:40Z 2015-11-19T03:00:09Z 2013-12 Thesis http://hdl.handle.net/10019.1/95478 en_ZA Stellenbosch University xii, 214 pages, illustrations application/pdf application/pdf Stellenbosch : Stellenbosch University |
| spellingShingle | Porosity Supramolecular chemistry Crystal engineering Inclusion compounds Absorption Porous materials Guest-exchange process Dissertations -- Chemistry and Polymer Science Grobler, Ilne Solid-state dynamics of porous materials |
| title | Solid-state dynamics of porous materials |
| title_full | Solid-state dynamics of porous materials |
| title_fullStr | Solid-state dynamics of porous materials |
| title_full_unstemmed | Solid-state dynamics of porous materials |
| title_short | Solid-state dynamics of porous materials |
| title_sort | solid state dynamics of porous materials |
| topic | Porosity Supramolecular chemistry Crystal engineering Inclusion compounds Absorption Porous materials Guest-exchange process Dissertations -- Chemistry and Polymer Science |
| url | http://hdl.handle.net/10019.1/95478 |
| work_keys_str_mv | AT groblerilne solidstatedynamicsofporousmaterials |