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Application of crystal field theory to the infrared spectra of transition metal complexes
[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2024
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| Summary: | [pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed. |
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