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Application of crystal field theory to the infrared spectra of transition metal complexes
[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2024
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| _version_ | 1867613729614462976 |
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| access_status_str | Open Access |
| author | Shephard, Gordon Seymour |
| author2 | Thornton, David A |
| author_browse | Shephard, Gordon Seymour Thornton, David A |
| author_facet | Thornton, David A Shephard, Gordon Seymour |
| author_sort | Shephard, Gordon Seymour |
| collection | Thesis |
| description | [pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/40435 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:40:46.901Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2024 |
| publishDateRange | 2024 |
| publishDateSort | 2024 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/40435 Application of crystal field theory to the infrared spectra of transition metal complexes Shephard, Gordon Seymour Thornton, David A Chemistry [pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed. 2024-07-23T12:46:36Z 2024-07-23T12:46:36Z 1973 2024-07-23T07:46:59Z Thesis / Dissertation Doctoral PhD http://hdl.handle.net/11427/40435 eng application/pdf Department of Chemistry Faculty of Science |
| spellingShingle | Chemistry Shephard, Gordon Seymour Application of crystal field theory to the infrared spectra of transition metal complexes |
| thesis_degree_str | Doctoral |
| title | Application of crystal field theory to the infrared spectra of transition metal complexes |
| title_full | Application of crystal field theory to the infrared spectra of transition metal complexes |
| title_fullStr | Application of crystal field theory to the infrared spectra of transition metal complexes |
| title_full_unstemmed | Application of crystal field theory to the infrared spectra of transition metal complexes |
| title_short | Application of crystal field theory to the infrared spectra of transition metal complexes |
| title_sort | application of crystal field theory to the infrared spectra of transition metal complexes |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/40435 |
| work_keys_str_mv | AT shephardgordonseymour applicationofcrystalfieldtheorytotheinfraredspectraoftransitionmetalcomplexes |